Arsenic
Chapter 296-848, WAC |
Effective
Date: 06/01/07 |
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Your Responsibility
To measure and minimize employee
exposure to inorganic arsenic.
IMPORTANT:
The sections listed in basic rules apply
to all employers covered by the scope of this chapter, WAC
296-848-100. To find additional sections that may apply to
you, go to the Scope, WAC 296-848-100,
and follow Table 1.

WAC 296-848-20010
Preventive practices
You must
1) Effectively communicate the hazards of
inorganic arsenic by doing both of the following:
- Keep container labels free of statements that
contradict or detract from the labels' hazard warning.
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Note:
- You may use labels required by other
laws, rules, or ordinances in addition to, or in combination
with, labels required by this section.
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You must
- Make sure shipping containers, storage containers,
and products containing inorganic arsenic are labeled, tagged,
or marked with this warning:
Danger
Contains Inorganic Arsenic
Cancer Hazard
Harmful if Inhaled or Swallowed
Use Only with Adequate Ventilation
or
Respiratory Protection |
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Note:
- You should keep containers tightly covered
when not in use to help prevent unnecessary exposure and
accidental spills.
- Contaminated items
should be handled and disposed of to prevent further exposure
in the workplace. For example, vacuuming or wet wiping
contaminated equipment helps prevent the release of dust
into the air.
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Reference:
Additional requirements are found in
other chapters:
- - For spills, leaks, or other releases,
go to Emergency Response, chapter 296-824
WAC.
- - For labeling go to:
- The Safety and Health Core Rules,
chapter 296-800
WAC, and find the section, Label containers
holding hazardous chemicals, WAC
296-800-17025;
and
- Material Safety Data Sheet and
Label Preparation, chapter 296-839
WAC.
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You must
2) Establish safe and effective housekeeping
and maintenance practices by doing all the following:
- Develop and keep a written housekeeping
and maintenance plan that lists appropriate frequencies for:
- - Housekeeping operations;
and
- - Cleaning and maintaining dust collection
equipment.
- Keep surfaces free of accumulations of inorganic
arsenic, to the degree feasible.
- When cleaning floors and other accessible
surfaces:
- - Use vacuuming or other cleaning methods
that minimize the release of inorganic arsenic into the
air.
- - Don't use compressed air.
- - Select vacuums that have high efficiency
particulate air (HEPA) filters.
- - Use and empty vacuums in a way that
minimizes the release of inorganic arsenic back into the
workplace.
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Note:
- Shoveling or brushing may be used only
when vacuuming or other cleaning methods haven't been
effective.
- Using non-HEPA vacuums will increase
inorganic arsenic contamination in air and on area surfaces.
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You must
- Maintain ventilation systems, including dust
collection equipment, to make sure they are effective. Do all
of the following:
- - Perform periodic inspections for effectiveness.
- - Periodically clean the equipment.
- - Keep a note of the most recent inspection
for effectiveness, and
cleaning or maintenance.
3) Prevent eye or skin contact with:
- Arsenic trichloride
and
- Liquid or particulate forms of inorganic
arsenic when contact could cause eye or skin irritation.
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Note:
- Arsenic trichloride
is corrosive and can be quickly absorbed through skin.
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WAC 296-848-20025
Washing facilities
You must
- Provide washing facilities for employees exposed
to inorganic arsenic.
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Reference:
- For additional washing facility requirements,
go to another chapter, the Safety and Health Core Rules,
chapter
296-800 WAC, and find the section titled, Provide
convenient and clean washing facilities, WAC
296-800-23025.
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WAC 296-848-20060
Exposure evaluations
IMPORTANT:
- This section applies when workplace operations
create potential airborne exposure to inorganic arsenic.
- When you conduct an exposure evaluation in
a workplace where an employee uses a respirator, the protection
provided by the respirator isn't considered.
- Following this section will fulfill the requirements
to identify and evaluate respiratory hazards found in chapter
296-841
WAC, Airborne contaminants.
You must
1) Conduct an employee exposure evaluation
to accurately determine airborne concentrations of inorganic arsenic
by completing Steps 1 through 5 of the Exposure Evaluation Process,
each time any of the following apply:
- No evaluation has been conducted.
- Changes have occurred in any of the following
areas that may result in new or increased exposures:
- - Production
- - Processes
- - Exposure controls such as ventilation
systems or work practices
- - Personnel.
- You have any reason to suspect new or increased
exposure may occur.
2) Provide affected employees and their designated
representatives an opportunity to observe exposure monitoring
during Step 4 of the Exposure Evaluation Process.
- Make sure observers don't interfere with
exposure measurements.
- Make sure observers are entitled to:
- - An explanation of your exposure measurement
and monitoring procedures
- - Observe all tasks of exposure measurement
performed at the workplace
and
- - Receive a copy of the exposure measurement
results when you obtain them or are allowed to record
the exposure measurement results, if made during observations.
- Make sure observers who enter areas with
inorganic arsenic exposure:
- - Are provided with and use the same
protective clothing, respirators, and other personal protective
equipment (PPE) that employees working in the area are
required to use
and
- - Follow safety and health requirements
that apply.
Exposure Evaluation Process
IMPORTANT:
- Following the Exposure Evaluation Process
isn't necessary when you have documentation conclusively demonstrating
inorganic arsenic exposures for a particular operation and material,
can't exceed the action level ( AL ) during any conditions reasonably
anticipated.
- Documentation can be based on quantitative
information such as soil test results or qualitative
information such as observations of how inorganic arsenic-containing
materials are handled.
- - Retain this documentation for as long
as you rely on it.
Step
1: Identify all employees who have potential airborne
exposure to inorganic arsenic in your workplace.
Step
2: Select employees from those identified in Step
1 who will have their 8-hour exposures monitored.
- Make sure the exposures of the employees
selected represent 8-hour exposures for all employees identified
in Step 1, including each job classification,
work area, and shift.
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Note:
- A written description of the procedure
for obtaining representative employee exposure monitoring
results needs to be kept as part of your exposure records
required by this chapter in Exposure records, WAC
296-848-20090. This description can be created while
completing Steps 2 through 4 of this exposure evaluation
process.
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Step
3: Determine
how you'll obtain employee exposure monitoring results.
- Select and use a method that meets the following
criteria for accuracy:
- - ±25%, with a confidence level of
95%, when concentrations are potentially at or above an 8-hour
time-weighted average of 10 micrograms per cubic meter (Fg/m3);
or
- - ±35%, with a confidence level of
95%, when concentrations are potentially between the eight-hour
time-weighted averages of 5 µg/m3 and 10
µg/m3.
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Note:
- Here are examples of methods that meet
this accuracy requirement.
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Step
4: Obtain employee exposure monitoring results by collecting
air samples representing employees identified in Step
1.
- Sample at least one shift representative
of the 8-hour exposure, for each employee selected in Step
2.
- Make sure samples are collected from each
selected employee's breathing zone.
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Note:
- You may use any sampling method that
meets the accuracies specified in Step
3. Examples of these methods include:
- - Real-time monitors that provide
immediate exposure monitoring results.
- - Equipment that collects samples
that are sent to a laboratory for analysis.
- The following are examples of methods
for collecting samples representative of 8-hour exposures.
- - Collect one or more continuous
samples, for example, a single 8-hour sample or four
2-hour samples.
- - Take a minimum of 4 to 7 brief
samples, such as 15-minute samples, during the work
shift and at times selected randomly.
- For work shifts longer than 8 hours,
monitor the continuous 8-hour portion of the shift expected
to have the highest average exposure concentration.
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Step 5:
Have the samples you collected analyzed to obtain monitoring
results representing 8-hour exposures.
- Go to the Scope of this chapter, WAC
296-848-100, and compare employee exposure monitoring results
to the values found in Step 1 and follow
Step 2 to determine if additional sections
of this chapter apply.
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Note:
- You may contact your local WISHA consultant
for help:
- - Interpreting data or other information.
- - Determining 8-hour employee exposure
monitoring results.
- To contact a WISHA consultant:
- - Go to the Safety and Health Core
Rules, chapter
296-800 WAC;
and
- - Find the Resources section, and
under "Other Resources," find Service Locations for
Labor and Industries.
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WAC 296-848-20070
Notification
You must
- Provide written notification of exposure monitoring
results, including notification about whether exposures exceed
the permissible exposure limit (PEL), to employees represented
by your exposure evaluation, within 5 business days after the
monitoring results become known to you.
- - In addition, when employee exposure
monitoring results are above the permissible exposure limit
(PEL), provide written notification of all the following
within 15 business days after these exposure monitoring
results become known to you.
- Corrective actions being taken and
a schedule for completion;
and
- Any reason why exposures can't be
lowered to below the PEL.
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Note:
- You can notify affected employees
either individually or post the notifications in areas
readily accessible to affected employees.
- When notifying employees about corrective
actions, your notification may refer them to a separate
document that's available and provides the required
information.
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WAC 296-848-20090
Exposure records
You must
- Establish and keep complete and accurate records
for all exposure monitoring conducted under this chapter. Make
sure the record includes, at least:
- - The name, Social Security number or
other unique identifier, and job classification of the employee
sampled and all other employees represented by the sampled
employee.
- - A description of the methods used to
obtain exposure monitoring results and evidence of the method's
accuracy.
- - A description of the procedure used
to obtain representative employee exposure monitoring results.
- - The date, number, duration, location,
and the result of each sample taken.
- - Any environmental conditions that could
affect exposure concentration measurements.
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Note:
- It's useful to record any personal
protective equipment worn by the employee in addition
to the type of respirator worn.
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You must
- Keep exposure monitoring records for at least
30 years.
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Reference:
- To see additional requirements for employee
exposure records including access and transfer requirements,
go to another chapter, Employee Medical and Exposure Records,
chapter 296-802
WAC.
- Exposure monitoring records need to
be kept longer than 30 years for employees participating
in medical monitoring. Go to Medical records, WAC
296-848-30080, found within this chapter.
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