Arsenic
Chapter 296-848, WAC |
Effective
Date: 06/01/07 |
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Your responsibility:
To protect employees from exposure
to inorganic arsenic by using feasible exposure controls and appropriate
respirators.
IMPORTANT:
- These sections apply when employee exposure
monitoring results are above the permissible exposure limit
(PEL) of 10 micrograms per cubic meter (µg/m3)
of air.

WAC 296-848-40005
Exposure control plan
IMPORTANT:
- Use of employee rotation to control exposures
isn't advisable since inorganic arsenic is a known carcinogen.
You must
- Establish and implement a complete written
exposure control plan that includes at least the following,
for exposure control areas:
- - A description of each operation releasing
inorganic arsenic, for example:
- Crew size.
- Current exposure controls.
- Materials processed.
- Machinery used.
- Operating procedures.
- Maintenance practices.
- - Exposure evaluation data.
- - A report of the technology considered
for exposure controls.
- - Engineering plans and studies used as
a basis for selecting exposure controls.
- - A detailed schedule for implementing:
- Feasible exposure controls, if immediate
implementation isn't possible.
- Changes to enhance current exposure
controls, when necessary.
- - An analysis of the effectiveness of
the exposure controls considered, when controls won't reduce
exposures to or below the permissible exposure limit (PEL).
- - Other relevant information.
- Review and update your exposure
control plan at least every 6 months to keep it current.
- Implement exposure controls on the
quickest schedule feasible if controls won't reduce
exposure to or below the PEL.
- Provide a copy of your exposure
control plan to affected employees and their designated
representatives, when they ask to review or copy it.
WAC 296-848-40020
Exposure controls
IMPORTANT:
- Use of employee rotation to control exposures
isn't advisable since inorganic arsenic is a known carcinogen.
- Respirators and other personal protective
equipment (PPE) don't substitute for feasible exposure controls.
You must
- Use feasible exposure controls to reduce exposures
to or below the permissible exposure limit (PEL), or as low
as achievable.
WAC 296-848-40025
Exposure control areas
You must
- Establish temporary or permanent exposure
control areas where airborne concentrations of inorganic arsenic
are above the permissible exposure limit (PEL) by doing all
the following:
- - Distinguish the boundaries of exposure
control areas from the rest of the workplace in any way
that minimizes employee access.
- - Allow only authorized personnel to enter
exposure control areas.
- - Post signs at access points to exposure
control areas that include this warning:
DANGER
Inorganic Arsenic
Cancer Hazard
Authorized Personnel Only
No Smoking or Eating
Respirator Required
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- - Make sure signs are kept clean and well
lit so they are easy to read.
- - Keep signs and areas near them free of
statements that contradict or detract from their message.
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Note:
- This requirement doesn't prevent
you from posting signs required by other laws, rules,
or ordinances.
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You must
- Make sure employees entering exposure control
areas have an appropriate respirator.
- Prevent all of the following activities from
occurring in exposure control areas unless they are conducted
in required lunchrooms, change rooms, or showers:
- - Eating food or drinking beverages.
- - Smoking.
- - Chewing tobacco or gum.
- - Applying cosmetics.
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Note:
- You may use permanent or temporary
enclosures, caution tape, ropes, painted lines on
surfaces, or other materials to visibly distinguish
exposure control areas or separate them from the rest
of the workplace.
- When distinguishing exposure
control areas, you should consider factors such as:
- - The level and duration of
airborne exposure.
- - Whether the area is permanent
or temporary.
- - The number of employees in
adjacent areas.
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Reference:
- To see other requirements for respirators
within this chapter, go to Respirators, WAC
296-848-40045.
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WAC 296-848-40030
Clean-up facilities and lunchrooms
You must
- Provide the following facilities for employees
who could experience eye or skin irritation from exposure to
inorganic arsenic or who work in exposure control areas:
- - Clean change rooms with separate storage
for street clothes and personal protective equipment (PPE).
- - Shower facilities.
- Make sure employees who could experience eye
or skin irritation from exposure to inorganic arsenic or who
work in exposure control areas:
- - Shower at the end of the work shift
and
- - Wash their hands and face before eating.
- Provide lunchrooms for employees working
in exposure control areas that are:
- - Located so they are readily accessible
to the employees.
- - Temperature controlled.
- - Under positive pressure compared to surrounding
areas.
- - Provided with a filtered air supply.
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Note:
Lunchrooms may be located within exposure
control areas, but are considered separate from the exposure
control area.
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- Do the following when exposures in exposure
control areas exceed an 8-hour time-weighted average of 100
micrograms of arsenic per cubic meter of air (µg/m3):
- - Provide facilities for employees working
in exposure control areas where they can remove excess contamination
from protective clothing and shoes.
- - Make sure employees vacuum protective
clothing and clean or change shoes before entering showers,
change rooms, or lunchrooms.
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Reference:
- To see additional requirements for
hygiene facilities:
- - Go to the Safety and Health
Core Rules, chapter
296-800 WAC.
- - Find Drinking water, bathrooms,
washing facilities, and waste disposal, WAC
296-800-230.
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WAC 296-848-40040
Personal protective equipment (PPE)
You must
- Provide, make sure employees use, and maintain
PPE as follows:
- - Provide clean and dry protective clothing
to employees who could experience eye or skin irritation
from exposure to inorganic arsenic or who work in exposure
control areas.
- - Provide impervious protective clothing to employees
exposed to arsenic trichloride.
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Note:
- Arsenic trichloride is corrosive and
can be rapidly absorbed through skin.
- Examples of protective clothing appropriate
for inorganic arsenic exposures include:
- - Coveralls or similar full-body
work clothing.
- - Gloves, and shoes or coverlets.
- - Face shields or vented goggles
when necessary to prevent eye irritation.
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You must
- - Make sure employees don't remove inorganic
arsenic from PPE by blowing or shaking.
- - Make sure protective clothing is removed:
- In change rooms
and
- At the end of the work shift.
- - Make sure contaminated protective clothing
that will be cleaned, laundered, or disposed of, is placed
in a closed container located in the change room.
- - Make sure the container prevents the release
of inorganic arsenic.
- - Launder protective clothing:
- At least weekly if employees work
in areas where exposure monitoring results of inorganic
arsenic are below an 8-hour time-weighted average concentration
of 100 micrograms per cubic meter (µg/m3)
or
- Daily if employees work in areas
where either exposure monitoring results of inorganic
arsenic are above an 8-hour time-weighted average concentration
of 100 µg/m3 or when more frequent
washing is needed to prevent skin irritation.
- - Maintain the effectiveness of PPE by repairing
or replacing it, as needed:
- Dispose of protective clothing if
it won't be repaired.
- Inform individuals who clean or launder protective
clothing about the possible health effects associated with inorganic
arsenic, including carcinogenic effects, by doing the following:
- - Provide the information in writing
and
- - Label containers of contaminated PPE
with the following warning:
Caution:
Clothing contaminated with
inorganic arsenic
Don't remove dust by blowing
or shaking
Dispose of inorganic arsenic
contaminated wash water as applicable local, state,
or federal regulations require
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Reference:
- To see additional Personal protective
equipment requirements go to the Safety and Health
Core Rules, chapter 296-800
WAC, and find the section titled, PPE, WAC
296-800-160.
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WAC 296-848-40045
Respirators
IMPORTANT:
- The requirements in this section are in addition
to the requirements found in other chapters:
You must
- Provide respirators and require that employees
use them in circumstances where exposure is above the permissible
exposure limit (PEL), including any of the following circumstances:
- - Employees are in an exposure control
area.
- - Feasible exposure controls are being
put in place.
- - Where you determine that exposure controls
aren't feasible.
- - Feasible exposure controls don't reduce
exposures to, or below, the PEL.
- - Emergencies.
- Provide high-efficiency particulate air (HEPA)
filters or N-, R-, or P-100 filters for powered air-purifying
respirators (PAPRs) and negative-pressure air-purifying respirators.
- Provide a powered air-purifying respirator
(PAPR) to employees required to use respirators when:
- - The employee chooses to use this type
of respirator or a licensed healthcare professional (LHCP)
recommends this type of respirator in their written opinion.
AND
- - It will provide proper protection.
- Follow these additional specifications for
inorganic arsenic compounds with significant vapor pressure
such as arsenic trichloride and arsenic phosphide.
- - Select front- or back-mounted gas masks
equipped with HEPA filters and acid gas canisters or any
full-facepiece supplied-air respirator, when concentrations
are at or below 500 mg/m3.
- - Select for powered air-purifying respirators
(PAPRs) and negative-pressure air-purifying respirators
equipped with HEPA (or equivalent) filters and acid gas
cartridges when concentrations are at or below 100.
- Prohibit the use of half-facepiece respirators
for protection against arsenic trichloride. This is because
arsenic trichloride is corrosive and rapidly absorbed through
the skin.
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Note:
- When selecting air-purifying respirators
for protection against inorganic arsenic, you'll need
to consider whether other contaminants could be present
at levels above permissible exposure limits and determine
if a combination filter/gas-sorbent cartridge or canister
is appropriate.
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