Benzene
Chapter 296-849, WAC |
Effective
Date: 06/01/07 |
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Your Responsibility
To measure and minimize employee exposure
to benzene
IMPORTANT:
To determine which requirements to follow
for your work tasks, go to Table
1 in the Scope of this chapter, WAC
296-849-100.
You must

WAC 296-849-11010
Preventive practices
You must
- Make sure containers of benzene in the workplace
are labeled, tagged, or marked with this warning:
DANGER
CONTAINS BENZENE
CANCER HAZARD
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Note:
- You should keep containers tightly covered
when not in use to prevent unnecessary exposure and accidental
spills.
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Reference:
- Additional requirements are found in
other chapters as follows:
- – For spills, leaks, or other
releases of benzene, go to Emergency Response, chapter
296-824 WAC.
- – For labeling go to:
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WAC 296-849-11020
Exposure control areas
You must
- Establish temporary or permanent exposure
control areas where airborne concentrations of benzene are above,
or can be reasonably expected to be above, the permissible exposure
limits (PELs) for benzene by doing all the following:
- – Post signs at access points to
exposure control areas that include this warning:
DANGER
Benzene
Cancer Hazard
Flammable - No Smoking
Authorized Personnel Only
Respirator Required
- – Distinguish the boundaries of
exposure control areas from the rest of the workplace in
any way that minimizes employee access.
- – Allow only
authorized personnel to enter exposure control areas.
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Note:
- You may use permanent or
temporary enclosures, caution tape, ropes, painted lines
on surfaces, or other materials to visibly distinguish
exposure control areas or separate them from the rest
of the workplace.
- When distinguishing exposure
control areas you should consider factors such as:
- – The level and duration
of airborne exposure.
- – Whether the area is permanent
or temporary.
- – The number of employees
in adjacent areas.
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Reference:
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WAC 296-849-11030
Exposure evaluations
IMPORTANT:
- When you conduct an exposure evaluation in
a workplace where an employee uses a respirator, the protection
provided by the respirator isn't considered.
- Following this section will fulfill
the requirements to identify and evaluate respiratory hazards
found in chapter
296-841 WAC, Airborne contaminants.
You must:
- Conduct an employee exposure evaluation to
accurately determine airborne concentrations of benzene by completing
Steps 1 through 7 of the exposure evaluation process, each time
any of the following apply:
- – No evaluation has been conducted.
- You have up to 30 days to complete
an evaluation once benzene is introduced into your
workplace.
- – Changes have occurred in any of
the following areas that may result in new or increased
exposures:
- Production.
- Processes.
- Exposure controls such as ventilation
systems or work practices.
- Personnel.
- – You have any reason to suspect
new or increased exposure may occur.
- – Spills, leaks, or other releases
have been cleaned up.
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Note:
- As part of your exposure
evaluation after cleanup, you will make sure exposure
monitoring results have returned to prerelease levels.
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Exposure Evaluation Process
IMPORTANT:
- If you are evaluating employee exposures
during cleaning and repair of barges and tankers that contained
benzene:
- – Collect samples that effectively
measure benzene concentrations that employees may be exposed
to
and
- – Skip to Step 7
- Following the exposure evaluation process
isn't necessary when you have documentation conclusively demonstrating
benzene exposures for a particular operation and material can't
exceed the action level (AL) during any conditions reasonably
anticipated.
- – Documentation can be based on
data or qualitative information, such as information about:
- The material
- How the material is handled
- The work conditions
- – Retain this documentation for
as long as you rely on it.
Step
1: Identify all employees who have potential airborne
exposure to benzene in your workplace.
Step
2: Identify operations where 15-minute exposures could
exceed benzene's short-term exposure limit (STEL) of 5 parts per
million (ppm).
- Include operations where it's reasonable
to expect high, 15-minute exposures, such as operations where:
- – Tanks are opened, filled, unloaded,
or gauged
- – Containers or process equipment
are opened
- – Benzene is used as a solvent for
cleaning
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Note:
- You may use monitoring
devices such as colorimetric indicator tubes or real-time
monitors to screen for activities where employee exposure
monitoring results could be high.
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Step
3: Select employees from those working in the operations
you identified in Step 2 who will have their
15-minute exposures measured.
Step
4: Select employees from those identified in Step
1 who will have their 8-hour exposures monitored.
- Make sure the exposures of the employees
selected represent 8-hour exposures for all
employees identified at Step 1, including
each job classification, work area, and shift.
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Note:
- A written description of
the procedure used for obtaining representative employee
exposure monitoring results needs to be kept as part of
your exposure records required by this chapter in Exposure
Records, WAC 296-849-11090.
This description can be created while completing Steps
3 through 6 of this exposure evaluation process.
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Step
5: Determine how you will obtain employee monitoring
results.
- Select and use a method that's accurate to
±25%, with a confidence level of 95%.
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Note:
- Here are examples of methods
that meet this accuracy requirement:
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Step 6: Obtain employee
exposure monitoring results by collecting air samples representing
employees identified at Step 1.
- Collect 15-minute samples from employees
selected at Step 3.
- Sample at least one shift representative
of the 8-hour exposure for each employee selected at Step
4.
- Make sure samples are collected from each
selected employee's breathing zone.
- Collecting area samples is permitted after
emergency releases.
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Note:
- You may use any sampling
method that meets the accuracy specified in Step
5. Examples of these methods include:
- – Real-time monitors that
provide immediate exposure monitoring results.
- – Equipment
that collects samples that are sent to a laboratory
for analysis.
- The following are examples of methods
of monitoring representative of 8-hour exposures:
- – Collect one or more continuous
samples, for example, a single 8-hour sample or four
2-hour samples.
- – Take a minimum of 5 brief
samples, such as 15-minute samples, during the work
shift and at times selected randomly.
- For work shifts longer than 8 hours,
monitor the continuous 8-hour portion of the shift expected
to have the highest average exposure concentration.
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Step 7: Have the samples
you collected analyzed to obtain monitoring results representing
8-hour and 15-minute exposures.
- Go to the scope of this chapter, WAC
296-849-100, and compare employee exposure monitoring results
to the values found in Step
2a and follow Step 2b
to determine if additional sections of this chapter apply.
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Note:
- You may contact your local
WISHA consultant for help:
- – Interpreting data or other
information.
- – Obtaining 8-hour or 15-minute
employee exposure monitoring results.
- To contact a WISHA consultant:
- – Go to another chapter, the
Safety and Health Core Rules, chapter
296-800 WAC, and find the Resources section, and
under "Other Resources," find service location
for Labor and Industries.
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WAC 296-849-11040
Personal protective equipment (PPE)
You must
- Make sure employees use appropriate PPE as
protection from skin or eye contact with liquid benzene.
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Note:
- Harmful amounts of benzene can enter
the body through skin and eye contact.
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WAC 296-849-11050
Training
You must
- Provide training and information to employees:
- – At the time of initial assignment
to a work area where benzene is present
and
- – At least every 12 months after
initial training for employees exposed to airborne concentrations
at or above the action level (AL) of 0.5 parts per million
(ppm).
- Make sure training and information includes
all of the following:
- – Specific information on benzene
for each hazard communication training topic. For the list
of hazard communication training topics, go to the Safety
and Health Core Rules, chapter
296-800 WAC, and find Inform and train your employees
about hazardous chemicals in your workplace, WAC
296-800-17030
and
- – An explanation of the contents
of each of the following and guidance about where to find
a copy:
and
- – A description of the medical
evaluation requirements of this chapter found in:
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Reference:
- To see additional training and information
requirements in other chapters, go to the:
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WAC 296-849-11065
Exposure monitoring observation
You must
(1) Provide affected
employees and their designated representatives an opportunity
to observe exposure monitoring during Step 6 of the exposure evaluation
process found in Exposure evaluations, WAC
296-849-11030.
(2) Make sure observers
who enter areas with benzene exposure:
- Are provided with and use the same protective
clothing, respirators, and other personal protective equipment
(PPE) that employees working in the area are required to use
and
- Follow safety and health requirements that
apply
WAC 296-849-11070
Notification
You must
- Provide written notification of exposure
monitoring results to the employees represented by your exposure
evaluation within 5 business days after the monitoring results
become known to you.
- – In addition, when employee exposure
monitoring results are above a permissible exposure limit
(PEL), provide written notification of all of the following
within 15 business days after these exposure monitoring
results become known to you:
- Corrective actions being taken and
a schedule for completion
and
- Any reason why exposures can't
be lowered to below the PELs for benzene.
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Note:
- You can notify employees either individually
or post the notifications in areas readily accessible
to affected employees.
- Posted notification may need specific
information that allows affected employees to determine
which monitoring results apply to them.
- Notification may be in any written
form, such as handwritten or e-mail.
- Notification may be limited to the
required information, such as exposure monitoring results.
- When notifying employees about corrective
actions, your notification may refer them to a separate
document that's available and provides the required information.
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WAC 296-849-11090
Exposure records
You must
- Establish and keep complete and accurate
records for all exposure monitoring conducted under this chapter.
Make sure the record includes at least:
- – The name, Social Security number,
or other unique identifier, and job classification of the
employee sampled and all other employees represented by
the sampled employee.
- – The type of respirator worn, if
any.
- – A description of the methods used
to obtain exposure monitoring results.
- – A description of the procedure
used to obtain representative employee exposure monitoring
results.
- – The date, number, duration, and
the result of each sample taken.
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Note:
- It's useful to record any personal protective
equipment worn by the employee, in addition to the type
of respirator worn.
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You must
- Keep exposure monitoring records for at least
30 years.
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Reference:
- To see additional requirements for employee
exposure records including access, and transfer requirements,
go to another chapter, Employee Medical and Exposure Records,
chapter
296-802 WAC.
- Exposure monitoring records need to
be kept longer than 30 years for employees participating
in medical monitoring, go to Medical records, WAC
296-849-12080, found within this chapter.
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