General Safety & Health Standards |
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Hazardous Materials,
Flammable and Combustible Liquids, Spray Finishing
Chapter 296-24 WAC, Part E
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NOTE: Dip Tanks has been moved from this section into Chapter 296-835, WAC
WAC
296-24-295
Compressed gases (general requirements).
296-24-29501
Inspection of compressed gas cylinders.
296-24-29503
Compressed gases.
296-24-29505
Safety relief devices for compressed gas containers.
296-24-310
Acetylene.
296-24-31001
Cylinders.
296-24-31003
Piped systems.
296-24-31005
Generators and filling cylinders.
296-24-315
Hydrogen.
296-24-31501
General.
296-24-31503
Gaseous hydrogen systems.
296-24-31505
Liquefied hydrogen systems.
296-24-320
Oxygen.
296-24-32001
Scope.
296-24-32003
Bulk oxygen systems.
296-24-325
Nitrous oxide.
296-24-330
Flammable and combustible liquids.
296-24-33001
Definitions.
296-24-33003
Scope.
296-24-33005
Tank storage.
296-24-33007
Piping, valves, and fittings.
296-24-33009
Container and portable tank storage.
296-24-33011
Industrial plants.
296-24-33013
Bulk plants.
296-24-33015
Service stations.
296-24-33017
Processing plants.
296-24-33019
Refineries, chemical plants, and distilleries.
296-24-370
Spray finishing using flammable and combustible materials.
296-24-37001
Definitions.
296-24-37003
Spray booths.
296-24-37005
Electrical and other sources of ignition.
296-24-37007
Ventilation.
296-24-37009
Flammable and combustible liquids--Storage and handling.
296-24-37011
Protection.
296-24-37013
Operations and maintenance.
296-24-37015
Fixed electrostatic apparatus.
296-24-37017
Electrostatic hand spraying equipment.
296-24-37019
Drying, curing, or fusion apparatus.
296-24-37021
Automobile undercoating in garages.
296-24-37023
Powder coating.
296-24-37025
Organic peroxides and dual component coatings.
296-24-37027
Scope.
296-24-405 Dip tanks.
296-24-450
Chlorine cylinders used in chlorinator systems.
WAC 296-24-295 Compressed
gases (general requirements).
[Order 73-5, 296-24-295, filed 5/9/73
and Order 73-4, 296-24-295, filed 5/7/73.]
WAC 296-24-29501
Inspection of compressed gas cylinders.
Each employer shall determine that compressed gas
cylinders under the employer's control are in a safe condition to the
extent that this can be determined by visual inspection. Visual and other
inspections shall be conducted as prescribed in the hazardous materials
regulations of the department of transportation (49 CFR Parts 171-179
and 14 CFR Part 103). Where those regulations are not applicable, visual
and other inspections shall be conducted in accordance with Compressed
Gas Association Pamphlets C-6-1968 and C-8-1962.
[Statutory Authority: Chapter 49.17 RCW.
94-15-096 (Order 94-07), 296-24-29501, filed 7/20/94, effective 9/20/94;
Order 73-5, 296-24-29501, filed 5/9/73 and Order 73-4, 296-24-29501, filed
5/7/73.]
WAC 296-24-29503
Compressed gases.
The in-plant handling, storage, and utilization of all compressed gases
in cylinders, portable tanks, rail tankcars, or motor vehicle cargo tanks
shall be in accordance with Compressed Gas Association Pamphlet P-1-1965.
[Order 73-5, 296-24-29503, filed 5/9/73
and Order 73-4, 296-24-29503, filed 5/7/73.]
WAC 296-24-29505
Safety relief devices for compressed gas containers.
Compressed gas cylinders, portable tanks, and cargo tanks shall have
pressure relief devices installed and maintained in accordance with Compressed
Gas Association Pamphlets S-1.1-1963 and 1965 addenda and S-1.2-1963.
[Order 73-5, 296-24-29505, filed 5/9/73
and Order 73-4, 296-24-29505, filed 5/7/73.]
WAC 296-24-310 Acetylene.
[Order 73-5, 296-24-310, filed 5/9/73
and Order 73-4, 296-24-310, filed 5/7/73.]
WAC 296-24-31001
Cylinders.
The in-plant transfer, handling, storage, and utilization of acetylene
in cylinders shall be in accordance with Compressed Gas Association Pamphlet
G-1-1966.
[Order 73-5, 296-24-31001, filed 5/9/73
and Order 73-4, 296-24-31001, filed 5/7/73.]
WAC 296-24-31003
Piped systems.
The piped systems for the in-plant transfer and distribution of acetylene
shall be designed, installed, maintained, and operated in accordance with
Compressed Gas Association Pamphlet G-1.3-1959.
[Order 73-5, 296-24-31003, filed 5/9/73
and Order 73-4, 296-24-31003, filed 5/7/73.]
WAC 296-24-31005
Generators and filling cylinders.
Plants for the generation of acetylene and the charging (filling) of
acetylene cylinders shall be designed, constructed, and tested in accordance
with the standards prescribed in Compressed Gas Association Pamphlet G-1.4-1966.
[Order 73-5, 296-24-31005, filed 5/9/73
and Order 73-4, 296-24-31005, filed 5/7/73.]
WAC 296-24-315 Hydrogen.
[Order 73-5, 296-24-315, filed 5/9/73
and Order 73-4, 296-24-315, filed 5/7/73.]
WAC 296-24-31501
General.
(1) Definitions as used in this section.
(a) Gaseous hydrogen system is one in which the hydrogen is
delivered, stored and discharged in the gaseous form to consumer's piping.
The system includes stationary or movable containers, pressure regulators,
safety relief devices, manifolds, interconnecting piping and controls.
The system terminates at the point where hydrogen at service pressure
first enters the consumer's distribution piping.
(b) Approved--Means unless otherwise indicated, listed or approved
by a nationally recognized testing laboratory. Refer to federal regulation
29 CFR 1910.7 for definition of nationally recognized testing laboratory.
(c) Listed--See "approved."
(d) ASME--American Society of Mechanical Engineers.
(e) DOT specifications--Regulations of the department of transportation
published in 49 CFR Chapter I.
(f) DOT regulations--See WAC
296-24-315.
(2) Scope.
(a) Gaseous hydrogen systems.
(i) WAC
296-24-31503 applies to the installation of gaseous hydrogen
systems on consumer premises where the hydrogen supply to
the consumer premises originates outside the consumer premises
and is delivered by mobile equipment.
(ii) WAC
296-24-31503 does not apply to gaseous hydrogen systems
having a total hydrogen content of less than four hundred
cubic feet, nor to hydrogen manufacturing plants or other
establishments operated by the hydrogen supplier or their
agent for the purpose of storing hydrogen and refilling portable
containers, trailers, mobile supply trucks, or tank cars.
(b) Liquefied hydrogen systems.
(i) WAC
296-24-31505 applies to the installation of liquefied
hydrogen systems on consumer premises.
(ii) WAC
296-24-31505 does not apply to liquefied hydrogen portable
containers of less than one hundred fifty liters (39.63 gallons)
capacity; nor to liquefied hydrogen manufacturing plants or
other establishments operated by the hydrogen supplier or
supplier's agent for the sole purpose of storing liquefied
hydrogen and refilling portable containers, trailers, mobile
supply trucks or tank cars.
[Statutory Authority: Chapter 49.17 RCW.
94-15-096 (Order 94-07), 296-24-31501, filed 7/20/94, effective 9/20/94;
88-23-054 (Order 88-25), 296-24-31501, filed 11/14/88; Order 73-5, 296-24-31501,
filed 5/9/73 and Order 73-4, 296-24-31501, filed 5/7/73.]
WAC 296-24-31503
Gaseous hydrogen systems.
(1) Design.
(a) Containers.
(i) Hydrogen containers shall comply with one of the following:
(A) Designed, constructed, and tested in accordance with appropriate
requirements of ASME Boiler and Pressure Vessel Code, Section VIII--Unfired
Pressure Vessels--1968.
(B) Designed, constructed, tested and maintained in accordance
with U.S. Department of Transportation specifications and regulations.
(ii) Permanently installed containers shall be provided with substantial
noncombustible supports on firm noncombustible foundations.
(iii) Each portable container shall be legibly marked with the name
"hydrogen" in accordance with "marking compressed gas containers to
identify the material contained" ANSI Z48.1-1954. Each manifolded
hydrogen supply unit shall be legibly marked with the name hydrogen
or a legend such as "this unit contains hydrogen."
(b) Safety relief devices.
(i) Hydrogen containers shall be equipped with safety relief devices
as required by the ASME Boiler and Pressure Vessel Code, Section VIII
Unfired Pressure Vessels, 1968 or the DOT specifications and regulations
under which the container is fabricated.
(ii) Safety relief devices shall be arranged to discharge upward
and unobstructed to the open air in such a manner as to prevent any
impingement of escaping gas upon the container, adjacent structure
of personnel. This requirement does not apply to DOT specification
containers having an internal volume of 2 cubic feet or less.
(iii) Safety relief devices or vent piping shall be designed or
located so that moisture cannot collect and freeze in a manner which
would interfere with proper operation of the device.
(c) Piping, tubing, and fittings.
(i) Piping, tubing, and fittings shall be suitable for hydrogen
service and for the pressures and temperatures involved. Case iron
pipe and fittings shall not be used.
(ii) Piping and tubing shall conform to Section 2-"Industrial Gas
and Air Piping"--Code for Pressure Piping, ANSI B31.1-1967 with
addenda B31.1-1969.
(iii) Joints in piping and tubing may be made by welding or brazing
or by use of flanged, threaded, socket, or compression fittings.
Gaskets and thread sealants shall be suitable for hydrogen service.
(d) Equipment assembly.
(i) Valves, gauges, regulators, and other accessories shall be
suitable for hydrogen service.
(ii) Installation of hydrogen systems shall be supervised by personnel
familiar with proper practices with reference to their construction
and use.
(iii) Storage containers, piping, valves, regulating equipment,
and other accessories shall be readily accessible, and shall be
protected against physical damage and against tampering.
(iv) Cabinets or housings containing hydrogen control or operating
equipment shall be adequately ventilated.
(v) Each mobile hydrogen supply unit used as part of a hydrogen
system shall be adequately secured to prevent movement.
(vi) Mobile hydrogen supply units shall be electrically bonded
to the system before discharging hydrogen.
(e) Marking. The hydrogen storage location shall be permanently placarded
as follows: "hydrogen--flammable gas--no smoking--no open flames," or
equivalent.
(f) Testing. After installations, all piping, tubing, and fittings
shall be tested and proved hydrogen gas tight at maximum operating pressure.
(2) Location.
(a) General.
(i) The system shall be located so that it is readily accessible
to delivery equipment and to authorized personnel.
(ii) Systems shall be located above ground.
(iii) Systems shall not be located beneath electric power lines.
(iv) Systems shall not be located close to flammable liquid piping
or piping of other flammable gases.
(v) Systems near aboveground flammable liquid storage shall be located
on ground higher then the flammable liquid storage except when dikes,
diversion curbs, grading, or separating solid walls are used to prevent
accumulation of flammable liquids under the system.
(b) Specific requirements.
(i) The location of a system, as determined by the maximum total
contained volume of hydrogen, shall be in the order of preference
as indicated by Roman numerals in
Table H-1.
| Nature
of location |
Size
of hydrogen system |
| Less than
3,000 CF |
3,000 CF
to 15,000 CF |
In
excess of 15,000 CF |
| Outdoors |
I |
I |
I. |
| In
a separate building |
II |
II |
II. |
| In
a special room |
III |
III |
Not permitted |
| Inside
buildings not in a special room and exposed to other occupancies |
IV |
Not permitted. |
Not permitted. |
(ii) The minimum distance in feet from a hydrogen system of indicated
capacity located outdoors, in separate buildings or in special rooms
to any specified outdoor exposure shall be in accordance with Table
H-2.
(iii) The distances in Table H-2 Items 1, 14, and 3 to 10 inclusive
do not apply where protective structures such as adequate fire walls
are located between the system and the exposure.
(iv) Hydrogen systems of less than 3,000 CF when located inside buildings
and exposed to other occupancies shall be situated in the building
so that the system will be as follows:
(A) In an adequately ventilated area as in (3)(b)(ii) of this section.
(B) Twenty feet from stored flammable materials or oxidizing gases.
(C) Twenty-five feet from open flames, ordinary electrical equipment
or other sources of ignition.
(D) Twenty-five feet from concentrations of people.
(E) Fifty feet from intakes of ventilation or air-conditioning
equipment and air compressors.
(F) Fifty feet from other flammable gas storage.
(G) Protected against damage or injury due to falling objects or
working activity in the area.
(H) More than one system of 3,000 CF or less may be installed in
the same room, provided the systems are separated by at least 50
feet. Each such system shall meet all of the requirements of this
section.
(3) Design consideration at specific locations.
(a) Outdoor locations.
(i) Where protective walls or roofs are provided, they shall be constructed
of noncombustible materials.
(ii) Where the enclosing sides adjoin each other, the area shall
be properly ventilated.
(iii) Electrical equipment shall meet the requirements for Class
I, Division 2 hazardous locations of WAC
296-24-95613.
(b) Separate buildings.
(i) Separate buildings shall be built of at least noncombustible
construction. Windows and doors shall be located so as to be readily
accessible in case of emergency. Windows shall be of glass or plastic
in metal frames.
(ii) Adequate ventilation to the outdoors shall be provided. Inlet
openings shall be located near the floor in exterior walls only. Outlet
openings shall be located at the high point of the room in exterior
walls or roof. Inlet and outlet openings shall each have minimum total
area of one square foot per 1,000 cubic feet of room volume. Discharge
from outlet openings shall be directed or conducted to a safe location.
(iii) Explosion venting shall be provided in exterior walls or roof
only. The venting area shall be equal to not less than 1 square foot
per 30 cubic feet of room volume and may consist of any one or any
combination of the following: Walls of light noncombustible material,
preferably single thickness, single strength glass; lightly fastened
hatch covers; lightly fastened swinging doors in exterior walls opening
outward; lightly fastened walls or roof designed to relieve at a maximum
pressure of 25 pounds per square foot.
(iv) There shall be no sources of ignition from open flames, electrical
equipment, or heating equipment.
(v) Electrical equipment shall meet the requirements of chapter
296-24 WAC Part L.
(vi) Heating, if provided, shall be by steam, hot water, or other
indirect means.
(c) Special rooms.
(i) Floor, walls, and ceiling shall have a fire-resistance rating
of at least 2 hours. Walls or partitions shall be continuous from
floor to ceiling and shall be securely anchored. At least one wall
shall be an exterior wall. Openings to other parts of the building
shall not be permitted. Windows and doors shall be in exterior walls
and shall be located so as to be readily accessible in case of emergency.
Windows shall be of glass or plastic in metal frames.
(ii) Ventilation shall be as provided in (3)(b)(ii) of this section.
(iii) Explosion venting shall be as provided in (3)(b)(iii) of this
section.
(iv) There shall be no sources of ignition from open flames, electrical
equipment or heating equipment.
(v) Electrical equipment shall meet the requirements of chapter
296-24 WAC Part L.
(vi) Heating, if provided, shall be by steam, hot water, or indirect
means.
(4) Operating instructions. For installations which require any operation
of equipment by the user, legible instructions shall be maintained at
operating locations.
(5) Maintenance.
(a) The equipment and functioning of each charged gaseous hydrogen
system shall be maintained in a safe operating condition in accordance
with the requirements of this section. The area within 15 feet of any
hydrogen container shall be kept free of dry vegetation and combustible
material.
TABLE H-2
| |
Size
of hydrogen system |
| Type
of outdoor exposure |
Less than
3,000 CF |
3,000 CF
to 15,000 CF |
In excess
of 15,000 CF |
| 1. Building or structure |
Wood frame construction* Heavy
timber, noncombustible or ordinary construction* Fire-restrictive
construction* |
10
0
0 |
25
10
0 |
50
**25
0 |
| 2. Wall openings |
Not above any part of a system
Above any part of a system |
10
25 |
10
25 |
10
25 |
| 3. Flammable liquids above
ground |
0 to 1,000 gallons In excess
of 1,000 gallons |
10
25 |
25
50 |
25
50 |
| 4. Flammable liquids below
ground--0 to 1,000 gallons |
Tank Vent or fill opening of
tank |
10
25 |
10
25 |
10
25 |
| 5. Flammable liquids below
ground--in excess of 1,000 gallons |
Tank Vent or fill opening of
tank |
20
25 |
20
25 |
20
25 |
| 6. Flammable gas storage, either
high pressure or low pressure |
0 to 15,000 CF capacity In
excess of 15,000 CF capacity |
10
25 |
25
50 |
25
50 |
| 7. Oxygen storage |
12,000 CF or less |
Refer
to NFPA No. 51, gas systems for welding and cutting (1969) |
| |
More than 12,000 CF |
Refer
to NFPA No. 566, bulk oxygen systems at consumer sites (1969) |
| 8. Fast burning
solids such as ordinary lumber, excelsior or paper |
50 |
50 |
25 |
| 9. Slow burning
solids such as heavy timber or coal |
25 |
25 |
25 |
| 10. Open flames
and other sources or ignition |
25 |
25 |
50 |
| 11. Air compressor
intakes or inlets to ventilating or air-condition equipment |
50 |
50 |
50 |
| 12. Concentration
of people |
25 |
50 |
50 |
| 13. Public sidewalks |
15 |
15 |
15 |
| 14. Line of adjoining
property which may be built upon |
5 |
5 |
5 |
*Refer to NFPA No. 220 standard types of building construction
for definitions of various types of construction. (1969 Ed.)
**But not less than one-half the height of adjacent side wall of the
structure.
***In congested areas such as offices, lunchrooms, locker rooms, time-clock
areas, and places of public assembly.
[Statutory Authority: Chapter 49.17 RCW.
91-24-017 (Order 91-07), 296-24-31503, filed 11/22/91, effective 12/24/91;
88-23-054 (Order 88-25), 296-24-31503, filed 11/14/88. Statutory Authority:
RCW 49.17.040 and 49.17.050. 85-10-004 (Order 85-09), 296-24-31503, filed
4/19/85; Order 76-6, 296-24-31503, filed 3/1/76; Order 73-5, 296-24-31503,
filed 5/9/73 and Order 73-4, 296-24-31503, filed 5/7/73.]
WAC 296-24-31505
Liquefied hydrogen systems.
(1) Design.
(a) Containers.
(i) Hydrogen containers shall comply with the following: Storage
containers shall be designed, constructed, and tested in accordance
with appropriate requirements of the ASME Boiler and Pressure Vessel
Code, Section VIII--Unfired Pressure Vessels (1968) or applicable
provisions of API Standard 620, Recommended Rules for Design and Construction
of Large, Welded, Low-Pressure Storage Tanks, Second Edition (June
1963) and Appendix R (April 1965).
(ii) Portable containers shall be designed, constructed and tested
in accordance with DOT specifications and regulations.
(b) Supports. Permanently installed containers shall be provided with
substantial noncombustible supports securely anchored on firm noncombustible
foundations. Steel supports in excess of 18 inches in height shall be
protected with a protective coating having a 2-hour fire-resistance
rating.
(c) Marking. Each container shall be legibly marked to indicate "liquefied
hydrogen--flammable gas."
(d) Safety relief devices.
(i) Stationary liquefied hydrogen containers shall be equipped with
safety relief devices sized in accordance with CGA Pamphlet S-1-1966,
Part 3, Safety Relief Device Standards for Compressed Gas Storage
Containers.
(A) Portable liquefied hydrogen containers complying with the U.S.
Department of Transportation regulations shall be equipped with
safety relief devices as required in the U.S. Department of Transportation
specifications and regulations. Safety relief devices shall be sized
in accordance with the requirements of CGA Pamphlet S-1-1966, Safety
Relief Device Standards, Part 1, Compressed Gas Cylinders and Part
2, Cargo and Portable Tank Containers.
(ii) Safety relief devices shall be arranged to discharge unobstructed
to the outdoors and in such a manner as to prevent impingement of
escaping liquid or gas upon the container, adjacent structures or
personnel. See (2)(a)(vi) of this section for venting of safety relief
devices in special locations.
(iii) Safety relief devices or vent piping shall be designed or located
so that moisture cannot collect and freeze in a manner which would
interfere with proper operation of the device.
(iv) Safety relief devices shall be provided in piping wherever liquefied
hydrogen could be trapped between closures
(e) Piping, tubing, and fittings.
(i) Piping, tubing, and fittings and gasket and thread sealants shall
be suitable for hydrogen service at the pressures and temperatures
involved. Consideration shall be given to the thermal expansion and
contraction of piping systems when exposed to temperature fluctuations
of ambient to liquefied hydrogen temperatures.
(ii) Gaseous hydrogen piping and tubing (above--20°F) shall conform
to the applicable sections of Pressure Piping Section 2--Industrial
Gas and Air Piping, ANSI B31.1-1967 with addenda B31.1-1969. Design
of liquefied hydrogen or cold (-20°F or below) gas piping shall use
Petroleum Refinery Piping ANSI B31.3-1966 or Refrigeration Piping
ANSI B31.5-1966 with addenda B31.5a-1968 as a guide.
(iii) Joints in piping and tubing shall preferably be made by welding
or brazing; flanged, threaded, socket, or suitable compression fittings
may be used.
(iv) Means shall be provided to minimize exposure of personnel to
piping operating at low temperatures and to prevent air condensate
from contacting piping, structural members, and surfaces not suitable
for cryogenic temperatures. Only those insulating materials which
are rated nonburning in accordance with ASTM Procedures D1692-68 may
be used. Other protective means may be used to protect personnel.
The insulation shall be designed to have a vapor-tight seal in the
outer covering to prevent the condensation of air and subsequent oxygen
enrichment within the insulation. The insulation material and outside
shield shall also be of adequate design to prevent attrition of the
insulation due to normal operating conditions.
(v) Uninsulated piping and equipment which operate at liquefied-hydrogen
temperature shall not be installed above asphalt surfaces or other
combustible materials in order to prevent contact of liquid air with
such materials. Drip pans may be installed under uninsulated piping
and equipment to retain and vaporize condensed liquid air.
(f) Equipment assembly.
(i) Valves, gauges, regulators, and other accessories shall be suitable
for liquefied hydrogen service and for the pressures and temperatures
involved.
(ii) Installation of liquefied hydrogen systems shall be supervised
by personnel familiar with proper practices and with reference to
their construction and use.
(iii) Storage containers, piping, valves, regulating equipment, and
other accessories shall be readily accessible and shall be protected
against physical damage and against tampering. A shutoff valve shall
be located in liquid product withdrawal lines as close to the container
as practical. On containers of over 2,000 gallons capacity, this shutoff
valve shall be of the remote control type with no connections, flanges,
or other appurtenances (other than a welded manual shutoff valve)
allowed in the piping between the shutoff valve and its connection
to the inner container.
(iv) Cabinets or housings containing hydrogen control equipment shall
be ventilated to prevent any accumulation of hydrogen gas.
(g) Testing.
(i) After installation, all field-erected piping shall be tested
and proved hydrogen gas-tight at operating pressure and temperature.
(ii) Containers if out of service in excess of 1 year shall be inspected
and tested as outlined in (1) of this section. The safety relief devices
shall be checked to determine if they are operable and properly set.
(h) Liquefied hydrogen vaporizers.
(i) The vaporizer shall be anchored and its connecting piping shall
be sufficiently flexible to provide for the effect of expansion and
contraction due to temperature changes.
(ii) The vaporizer and its piping shall be adequately protected on
the hydrogen and heating media sections with safety relief devices.
(iii) Heat used in a liquefied hydrogen vaporizer shall be indirectly
supplied utilizing media such as air, steam, water, or water solutions.
(iv) A low temperature shutoff switch shall be provided in the vaporizer
discharge piping to prevent flow of liquefied hydrogen in the event
of the loss of the heat source.
(i) Electrical systems.
(i) Electrical wiring and equipment located within 3 feet of a point
where connections are regularly made and disconnected, shall
meet the requirements of chapter
296-24 WAC Part L for Class I, Division 1 locations.
(ii) Except as provided in (l) of this section, electrical wiring,
and equipment located within 25 feet of a point where connections
are regularly made and disconnected or within 25 feet of a
liquid hydrogen storage container, shall meet the requirements
of chapter
296-24 WAC Part L for Class I, Division 2 locations. When
equipment approved for Class I, environments is not commercially
available, the equipment may be:
(A) Purged or ventilated in accordance with NFPA No. 496-1967,
Standard for Purged Enclosures for Electrical Equipment in Hazardous
Locations,
(B) Intrinsically safe, or
(C) Approved for Class I, Group C atmospheres. This requirement
does not apply to electrical equipment which is installed on mobile
supply trucks or tank cars from which the storage container is filled.
(j) Bonding and grounding. The liquefied hydrogen container and associated
piping shall be electrically bonded and grounded.
(2) Location of liquefied hydrogen storage.
(a) General requirements.
(i) The storage containers shall be located so that they are readily
accessible to mobile supply equipment at ground level and to authorized
personnel.
(ii) The containers shall not be exposed by electric power lines,
flammable liquid lines, flammable gas lines, or lines carrying oxidizing
materials.
(iii) When locating liquefied hydrogen storage containers near above-ground
flammable liquid storage or liquid oxygen storage, locate the liquefied
hydrogen container on ground higher than flammable liquid storage
or liquid oxygen storage.
(iv) Where it is necessary to locate the liquefied hydrogen container
on ground that is level with or lower than adjacent flammable liquid
storage or liquid oxygen storage, suitable protective means shall
be taken (such as by diking, diversion, curbs, grading), with respect
to the adjacent flammable liquid storage or liquid oxygen storage,
to prevent accumulation of liquids within 50 feet of the liquefied
hydrogen container.
(v) Storage sites shall be fenced and posted to prevent entrance
by unauthorized personnel. Sites shall also be placarded as follows:
"Liquefied hydrogen--Flammable gas--No smoking--No open flames."
(vi) If liquefied hydrogen is located in (as specified in Table H-3)
a separate building, in a special room, or inside buildings when not
in a special room and exposed to other occupancies, containers shall
have the safety relief devices vented unobstructed to the outdoors
at a minimum elevation of 25 feet above grade to a safe location as
required in (l)(d)(ii) of this section.
(b) Specific requirements.
(i) The location of liquefied hydrogen storage, as determined by
the maximum total quantity of liquefied hydrogen, shall be in the
order of preference as indicated by Roman numerals in the following
Table H-3.
TABLE
H-3
MAXIMUM
TOTAL QUANTITY OF LIQUEFIED HYDROGEN STORAGE PERMITTED
| Nature of
location |
Size
of hydrogen storage (capacity in gallons) |
| |
39.63 (150
liters) to 50 |
51 to 300 |
301 to 600 |
In excess
of 600 |
| Outdoors
In a separate building
In a special room |
I
II
III |
I
II
III |
I
II
Not permitted. |
I
Not permitted. Not permitted. |
Note: This table does not apply to the storage in dewars of the
type generally used in laboratories for experimental purposes.
(ii) The minimum distance in feet from liquefied hydrogen systems
of indicated storage capacity located outdoors, in a separate building,
or in a special room to any specified exposure shall be in accordance
with Table H-4.
TABLE H-4
MINIMUM DISTANCE
(FEET) FROM LIQUEFIED HYDROGEN SYSTEMS TO EXPOSURE
| Type of exposure |
Liquefied
hydrogen storage (capacity in gallons) |
| |
39.63 (150
liters) to 3,500 |
3,501 to
15,000 |
15,001 to
30,000 |
| 1.
Fire-resistive building and fire walls*
2. Noncombustible
building*
3. Other
buildings*
4. Wall openings,
air-compressor intakes, inlets for air-conditioning or ventilating
equipment
5. Flammable
liquids (aboveground) and vent or fill openings if below ground)
see 513 and 514)
6. Between
stationary liquefied hydrogen containers
7. Flammable
gas storage
8. Liquid
oxygen storage and other oxidizers (see 513 and 514)
9. Combustible
solids
10. Open
flames, smoking, and welding
11. Concentrations
of people**
12. Public
ways, railroads, and property lines |
5
25
50
75
50
5
50
100
50
50
75
25 |
5
50
75
75
75
5
75
100
75
50
75
50 |
5
75
100
75
100
5
100
100
100
50
75
75 |
* Refer to standard types of
building construction, NFPA No. 220-1969 for definitions of various
types of construction.
** In congested areas such
as offices, lunchrooms, locker rooms, time-clock areas, and places of
public assembly.
Note 1: The distance in
Nos. 2, 3, 5, 7, 9, and 12 in Table H-4 may be reduced where protective
structures, such as firewalls equal to height of top of the container,
to safeguard the liquefied hydrogen storage system, are located between
the liquefied hydrogen storage installation and the exposure.
Note 2: Where protective
structures are provided, ventilation and confinement of product should
be considered. The 5-foot distance in Nos. 1 and 6 facilitates maintenance
and enhances ventilation.
(c) Handling of liquefied hydrogen inside buildings other than separate
buildings and special rooms. Portable liquefied hydrogen containers
of 50 gallons or less capacity as permitted in Table H-3 and in compliance
with (2)(a)(vi) of this section when housed inside buildings not located
in a special room and exposed to other occupancies shall comply with
the following minimum requirements:
(i) Be located 20 feet from flammable liquids and readily combustible
materials such as excelsior or paper.
(ii) Be located 25 feet from ordinary electrical equipment and other
sources of ignition including process or analytical equipment.
(iii) Be located 25 feet from concentrations of people.
(iv) Be located 50 feet from intakes of ventilation and air-conditioning
equipment or intakes of compressors.
(v) Be located 50 feet from storage of other flammable-gases or storage
of oxidizing gases.
(vi) Containers shall be protected against damage or injury due to
falling objects or work activity in the area.
(vii) Containers shall be firmly secured and stored in an upright
position.
(viii) Welding or cutting operations, and smoking shall be prohibited
while hydrogen is in the room.
(ix) The area shall be adequately ventilated. Safety relief devices
on the containers shall be vented directly outdoors or to a suitable
hood. See (1)(d)(ii) of this section and (2)(a)(vi) of this section.
(3) Design considerations at specific locations.
(a) Outdoor locations.
(i) Outdoor location shall mean outside of any building or structure,
and includes locations under a weather shelter or canopy provided
such locations are not enclosed by more than two walls set at right
angles and are provided with vent-space between the walls and vented
roof or canopy.
(ii) Roadways and yard surfaces located below liquefied hydrogen
piping, from which liquid air may drop, shall be constructed of noncombustible
materials.
(iii) If protective walls are provided, they shall be constructed
of noncombustible materials and in accordance with the provisions
of (3)(a)(i) of this section as applicable.
(iv) Electrical wiring and equipment shall comply with chapter
296-24 WAC Part L.
(v) Adequate lighting shall be provided for nighttime transfer operation.
(b) Separate buildings.
(i) Separate buildings shall be of light noncombustible construction
on a substantial frame. Walls and roofs shall be lightly fastened
and designed to relieve at a maximum internal pressure of 25 pounds
per square foot. Windows shall be of shatterproof glass or plastic
in metal frames. Doors shall be located in such a manner that they
will be readily accessible to personnel in an emergency.
(ii) Adequate ventilation to the outdoors shall be provided. Inlet
openings shall be located near the floor level in exterior walls only.
Outlet openings shall be located at the high point of the room in
exterior walls or roof. Both the inlet and outlet vent openings shall
have a minimum total area of 1 square foot per 1,000 cubic feet of
room volume. Discharge from outlet openings shall be directed or conducted
to a safe location.
(iii) There shall be no sources of ignition.
(iv) Electrical wiring and equipment shall comply with chapter
296-24 WAC Part L.
(v) Heating, if provided, shall be by steam, hot water, or other
indirect means.
(c) Special rooms.
(i) Floors, walls, and ceilings shall have a fire resistance rating
of at least 2 hours. Walls or partitions shall be continuous from
floor to ceiling and shall be securely anchored. At least one wall
shall be an exterior wall. Openings to other parts of the building
shall not be permitted. Windows and doors shall be in exterior walls
and doors shall be located in such a manner that they will be accessible
in an emergency. Windows shall be of shatterproof glass or plastic
in metal frames.
(ii) Ventilation shall be as provided in (3)(b)(ii) of this section.
(iii) Explosion venting shall be provided in exterior walls or roof
only. The venting area shall be equal to not less than 1 square foot
per 30 cubic feet of room volume and may consist of any one or any
combination of the following: Walls of light noncombustible material;
lightly fastened hatch covers; lightly fastened swinging doors opening
outward in exterior walls; lightly fastened walls or roofs designed
to relieve at a maximum pressure of 25 pounds per square foot.
(iv) There shall be no sources of ignition.
(v) Electrical wiring and equipment shall comply with chapter
296-24 WAC Part L.
(vi) Heating, if provided, shall be steam, hot water, or by other
indirect means.
(4) Operating instructions.
(a) Written instructions. For installation which require any operation
of equipment by the user, legible instructions shall be maintained at
operating locations.
(b) Attendant. A qualified person shall be in attendance at all times
while the mobile hydrogen supply unit is being unloaded.
(c) Security. Each mobile liquefied hydrogen supply unit used as part
of a hydrogen system shall be adequately secured to prevent movement.
(d) Grounding. The mobile liquefied hydrogen supply unit shall be grounded
for static electricity.
(5) Maintenance.
(a) The equipment and functioning of each charged liquefied hydrogen
system shall be maintained in a safe operating condition in accordance
with the requirements of this section. Weeds or similar combustibles
shall not be permitted within 25 feet of any liquified hydrogen equipment.
[Statutory Authority: Chapter 49.17 RCW.
91-24-017 (Order 91-07), 296-24-31505, filed 11/22/91, effective 12/24/91;
88-23-054 (Order 88-25), 296-24-31505, filed 11/14/88. Statutory Authority:
RCW 49.17.040 and 49.17.050. 85-10-004 (Order 85-09), 296-24-31505, filed
4/19/85; Order 76-6, 296-24-31505, filed 3/1/76; Order 73-5, 296-24-31505,
filed 5/9/73 and Order 73-4, 296-24-31505, filed 5/7/73.]
WAC 296-24-320 Oxygen.
[Order 73-5, 296-24-320, filed 5/9/73
and Order 73-4, 296-24-320, filed 5/7/73.]
WAC 296-24-32001
Scope.
This section applies to the installation of bulk oxygen systems on industrial
and institutional consumer premises. This section does not apply
to oxygen manufacturing plants or other establishments operated
by the oxygen supplier or supplier's agent for the purpose of
storing oxygen and refilling portable containers, trailers, mobile
supply trucks, or tank cars, nor to systems having capacities
less than those stated in WAC
296-24-32003(1).
[Statutory Authority: Chapter 49.17 RCW.
94-15-096 (Order 94-07), 296-24-32001, filed 7/20/94, effective 9/20/94;
Order 73-5, 296-24-32001, filed 5/9/73 and Order 73-4, 296-24-32001, filed
5/7/73.]
WAC 296-24-32003
Bulk oxygen systems.
(1) Definitions. As used in this section: A bulk oxygen system is an
assembly of equipment, such as oxygen storage containers, pressure regulators,
safety devices, vaporizers, manifolds, and interconnecting piping, which
has storage capacity of more than 13,000 cubic feet of oxygen, normal
temperature and pressure (NTP), connected in service or ready for service,
or more than 25,000 cubic feet of oxygen (NTP) including unconnected reserves
on hand at the site. The bulk oxygen system terminates at the point where
oxygen at service pressure first enters the supply line. The oxygen containers
may be stationary or movable, and the oxygen may be stored as gas or liquid.
(2) Location.
(a) General. Bulk oxygen storage systems shall be located above ground
out of doors, or shall be installed in a building of noncombustible
construction, adequately vented, and used for that purpose exclusively.
The location selected shall be such that containers and associated equipment
shall not be exposed by electric power lines, flammable or combustible
liquid lines, or flammable gas lines.
(b) Accessibility. The system shall be located so that it is readily
accessible to mobile supply equipment at ground level and to authorized
personnel.
(c) Leakage. Where oxygen is stored as a liquid, noncombustible surfacing
shall be provided in an area in which any leakage of liquid oxygen might
fall during operation of the system and filling of a storage container.
For purposes of these standards, asphaltic or bituminous paving is considered
to be combustible.
(d) Elevation. When locating bulk oxygen systems near above ground
flammable or combustible liquid storage which may be either indoors
or outdoors, it is advisable to locate the system on ground higher than
the flammable or combustible liquid storage.
(e) Dikes. Where it is necessary to locate a bulk oxygen system on
ground lower than adjacent flammable or combustible liquid storage suitable
means shall be taken (such as by diking, diversion curbs, or grading)
with respect to the adjacent flammable or combustible liquid storage
to prevent accumulation of liquids under the bulk oxygen system.
(3) Distance between systems and exposures.
(a) General. The minimum distance from any bulk oxygen storage container
to exposures, measured in the most direct line except as indicated in
(3)(f) and (g) of this section shall be as indicated in (3)(b) to (r)
of this section inclusive.
(b) Combustible structures. Fifty feet from any combustible structures.
(c) Fire resistive structures. Twenty-five feet from any structures
with fire-resistive exterior walls or sprinklered buildings or other
construction, but not less than one-half the height of adjacent side
wall of the structure.
(d) Openings. At least 10 feet from any opening in adjacent walls of
fire resistive structures. Spacing from such structures shall be adequate
to permit maintenance, but shall not be less than 1 foot.
(e) Flammable liquid storage above ground.
| Distance
(feet) |
Capacity
(gallons) |
| 50
90 |
0-1000
1001 or more- |
(f) Flammable liquid storage below ground.
| Distance
measured horizontally from oxygen storage container to flammable
liquid tank (feet) |
Distance
from oxygen storage container to filling and vent connections or
openings to flammable liquid tank (feet) |
Capacity
(gallons) |
| 15
30 |
50
50 |
0-1000
1001 or more |
(g) Combustible liquid storage above ground.
| Distance
(feet) |
Capacity
(gallons) |
| 25
50 |
0-1000
1001 or more- |
(h) Combustible liquid storage below ground.
| Distance
measured horizontally from oxygen storage container to combustible
liquid tank (feet) |
Distance
from oxygen storage container to filling and vent connections
or openings to combustible liquid tank (feet) |
| 15 |
40 |
(i) Flammable gas storage. (Such as compressed flammable gases, liquefied
flammable gases and flammable gases in low pressure gas holders):
| Distance
(feet) |
Capacity
(cu. ft. NTP) |
| 50
90 |
Less
than 5000
5000 or more |
(j) Highly combustible materials. Fifty feet from solid materials which
burn rapidly, such as excelsior or paper.
(k) Slow-burning materials. Twenty-five feet from solid materials which
burn slowly, such as coal and heavy timber.
(l) Ventilation. Seventy-five feet in one direction and 35 feet in
approximately 90° direction from confining walls (not including firewalls
less than 20 feet high) to provide adequate ventilation in courtyards
and similar confining areas.
(m) Congested areas. Twenty-five feet from congested areas such as
offices, lunchrooms, locker rooms, time clock areas, and similar locations
where people may congregate.
(n) Public areas. Fifty feet from places of public assembly.
(o) Patients. Fifty feet from areas occupied by nonambulatory patients.
(p) Sidewalks. Ten feet from any public sidewalk.
(q) Adjacent property. Five feet from any line of adjoining property.
(r) Exceptions. The distances in (3)(b), (c), (e) to (k) inclusive,
and (p) and (q) of this section do not apply where protective structures
such as firewalls of adequate height to safeguard the oxygen storage
systems are located between the bulk oxygen storage installation and
the exposure. In such cases, the bulk oxygen storage installation may
be a minimum distance of 1 foot from the firewall.
(4) Storage containers.
(a) Foundations and supports. Permanently installed containers shall
be provided with substantial noncombustible supports on firm noncombustible
foundations.
(b) Construction--Liquid. Liquid oxygen storage containers shall be
fabricated from materials meeting the impact test requirements of paragraph
UG-84 of ASME Boiler and Pressure Vessel Code, Section VIII--Unfired
Pressure Vessels--1968. Containers operating at pressures above 15 pounds
per square inch gage (p.s.i.g.) shall be designed, constructed, and
tested in accordance with appropriate requirements of ASME Boiler and
Pressure Vessel Code, Section VII--Unfired Pressure Vessels--1968. Insulation
surrounding the liquid oxygen container shall be noncombustible.
(c) Construction--Gaseous. High-pressure gaseous oxygen containers
shall comply with one of the following:
(i) Designed, constructed, and tested in accordance with appropriate
requirements of ASME Boiler and Pressure Vessel Code, Section VIII--Unfired
Pressure Vessels--1968.
(ii) Designed, constructed, tested, and maintained in accordance
with DOT specifications and regulations.
(5) Piping, tubing, and fittings.
(a) Selection. Piping, tubing, and fittings shall be suitable for oxygen
service and for the pressures and temperatures involved.
(b) Specification. Piping and tubing shall conform to Section 2--Gas
and Air Piping Systems of Code for Pressure Piping, ANSI, B31.1-1967
with addenda B31.10a-1969.
(c) Fabrication. Piping or tubing for operating temperatures below
-20°F shall be fabricated from materials meeting the impact test requirements
of paragraph UG-84 of ASME Boiler and Pressure Vessel Code, Section
VIII--Unfired Pressure Vessels--1968, when tested at the minimum operating
temperature to which the piping may be subjected in service.
(6) Safety relief devices.
(a) General. Bulk oxygen storage containers, regardless of design pressure
shall be equipped with safety relief devices as required by the ASME
code or the DOT specifications and regulations.
(b) DOT containers. Bulk oxygen storage containers designed and constructed
in accordance with DOT specification shall be equipped with safety relief
devices as required thereby.
(c) ASME containers. Bulk oxygen storage containers designed and constructed
in accordance with the ASME Boiler and Pressure Vessel Code, Section
VIII--Unfired Pressure Vessel--1968 shall be equipped with safety relief
devices meeting the provisions of the Compressed Gas Association Pamphlet
"Safety Relief Device Standards for Compressed Gas Storage Containers,"
S-1, Part 3.
(d) Insulation. Insulation casings on liquid oxygen containers shall
be equipped with suitable safety relief devices.
(e) Reliability. All safety relief devices shall be so designed or
located that moisture cannot collect and freeze in a manner which would
interfere with proper operation of the device.
(7) Liquid oxygen vaporizers.
(a) Mounts and couplings. The vaporizer shall be anchored and its connecting
piping be sufficiently flexible to provide for the effect of expansion
and contraction due to temperature changes.
(b) Relief devices. The vaporizer and its piping shall be adequately
protected on the oxygen and heating medium sections with safety relief
devices.
(c) Heating. Heat used in an oxygen vaporizer shall be indirectly supplied
only through media such as steam, air, water, or water solutions which
do not react with oxygen.
(d) Grounding. If electric heaters are used to provide the primary
source of heat, the vaporizing system shall be electrically grounded.
(8) Equipment assembly and installation.
(a) Cleaning. Equipment making up a bulk oxygen system shall be cleaned
in order to remove oil, grease or other readily oxidizable materials
before placing the system in service.
(b) Joints. Joints in piping and tubing may be made by welding or by
use of flanged, threaded, slip, or compression fittings. Gaskets or
thread sealants shall be suitable for oxygen service.
(c) Accessories. Valves, gages, regulators, and other accessories shall
be suitable for oxygen service.
(d) Installation. Installation of bulk oxygen systems shall be supervised
by personnel familiar with proper practices with reference to their
construction and use.
(e) Testing. After installation all field erected piping shall be tested
and proved gas tight at maximum operating pressure. Any medium used
for testing shall be oil free and nonflammable.
(f) Security. Storage containers, piping, valves, regulating equipment,
and other accessories shall be protected against physical damage and
against tampering.
(g) Venting. Any enclosure containing oxygen control or operating equipment
shall be adequately vented.
(h) Placarding. The bulk oxygen storage location shall be permanently
placarded to indicate: "oxygen--no smoking--no open flames," or an equivalent
warning.
(i) Electrical wiring. Bulk oxygen installations are not hazardous
locations as defined and covered by chapter
296-24 WAC Part L. Therefore, general purpose or weatherproof
types of electrical wiring and equipment are acceptable depending
upon whether the installation is indoors or outdoors. Such equipment
shall be installed according to chapter
296-24 WAC Part L.
(9) Operating instructions. For installations which require any operation
of equipment by the user, legible instructions shall be maintained at
operating locations.
(10) Maintenance.
(a) The equipment and functioning of each charged bulk oxygen system
shall be maintained in a safe operating condition in accordance with
the requirements of this section. Wood and long dry grass shall be cut
back within 15 feet of any bulk oxygen storage container.
[Statutory Authority: Chapter 49.17 RCW.
91-24-017 (Order 91-07), 296-24-32003, filed 11/22/91, effective 12/24/91.
Statutory Authority: RCW 49.17.040 and 49.17.050. 85-10-004 (Order 85-09),
296-24-32003, filed 4/19/85; Order 76-6, 296-24-32003, filed 3/1/76; Order
73-5, 296-24-32003, filed 5/9/73 and Order 73-4, 296-24-32003, filed 5/7/73.]
WAC 296-24-325 Nitrous
oxide.
The piped systems for the in-plant transfer and distribution of nitrous
oxide shall be designed, installed, maintained, and operated in accordance
with Compressed Gas Association Pamphlet G8.1-1964.
[Order 73-5, 296-24-325, filed 5/9/73
and Order 73-4, 296-24-325, filed 5/7/73.]
WAC 296-24-330 Flammable
and combustible liquids.
[Order 73-5, 296-24-330, filed 5/9/73
and Order 73-4, 296-24-330, filed 5/7/73.]
WAC 296-24-33001
Definitions.
The following definitions are applicable to all sections of this chapter
which include WAC
296-24-330 in the section number.
(1) Aerosol shall mean a material which is dispensed from its
container as a mist, spray, or foam by a propellant under pressure.
(2) Atmospheric tank shall mean a storage tank which has been
designed to operate at pressures from atmospheric through 0.5 p.s.i.g.
(3) Automotive service station shall mean that portion of property
where flammable or combustible liquids used as motor fuels are stored
and dispensed from fixed equipment into the fuel tanks of motor vehicles
and shall include any facilities available for the sale and service of
tires, batteries, and accessories, and for minor automotive maintenance
work. Major automotive repairs, painting, body and fender work are excluded.
(4) Basement shall mean a story of a building or structure having
one-half or more of its height below ground level and to which access
for fire fighting purposes is unduly restricted.
(5) Boiling point shall mean the boiling point of a liquid at
a pressure of 14.7 pounds per square inch absolute (p.s.i.a.) (760 mm.).
Where an accurate boiling point is unavailable for the material in question,
or for mixtures which do not have a constant boiling point, for purposes
of this section the ten percent point of a distillation performed in accordance
with the Standard Method of Test for Distillation of Petroleum Products,
ASTM D-86-62, may be used as the boiling point of the liquid.
(6) Boilover shall mean the expulsion of crude oil (or certain
other liquids) from a burning tank. The light fractions of the crude oil
burnoff producing a heat wave in the residue, which on reaching a water
strata may result in the expulsion of a portion of the contents of the
tank in the form of froth.
(7) Bulk plant shall mean that portion of a property where flammable
or combustible liquids are received by tank vessel, pipelines, tank car,
or tank vehicle, and are stored or blended in bulk for the purpose of
distributing such liquids by tank vessel, pipeline, tank car, tank vehicle,
or container.
(8) Chemical plant shall mean a large integrated plant or that
portion of such a plant other than a refinery or distillery where flammable
or combustible liquids are produced by chemical reactions or used in chemical
reactions.
(9) Closed container shall mean a container as herein defined,
so sealed by means of a lid or other device that neither liquid nor vapor
will escape from it at ordinary temperatures.
(10) Crude petroleum shall mean hydrocarbon mixtures that have
a flash point below 150°F and which have not been processed in a refinery.
(11) Distillery shall mean a plant or that portion of a plant
where flammable or combustible liquids produced by fermentation are concentrated,
and where the concentrated products may also be mixed, stored, or packaged.
(12) Fire area shall mean an area of a building separated from
the remainder of the building by construction having a fire resistance
of at least one hour and having all communicating openings properly protected
by an assembly having a fire resistance rating of at least one hour.
(13) Fire resistance or fire resistive construction shall
mean construction to resist the spread of fire.
(14) Flammable aerosol shall mean an aerosol which is required
to be labeled "Flammable" under the Federal Hazardous Substances
Labeling Act (15 U.S.C. 1261). For the purposes of WAC
296-24-33009, such aerosols are considered Class IA liquids.
(15) "Flashpoint" means the minimum temperature at which a liquid
gives off vapor within a test vessel in sufficient concentration to form
an ignitable mixture with air near the surface of the liquid, and shall
be determined as follows:
(a) For a liquid which has a viscosity of less than 45 SUS at 100°F
(37.8°C), does not contain suspended solids, and does not have a tendency
to form a surface film while under test, the procedure specified in
the Standard Method of Test for Flashpoint by Tag Closed Tester (ASTM
D-56-70) shall be used.
(b) For a liquid which has a viscosity of 45 SUS or more at 100°F (37.8°C),
or contains suspended solids, or has a tendency to form a surface film
while under test, the Standard Method of Test for Flashpoint by Pensky-Martens
Closed Tester (ASTM D-93-71) shall be used, except that the methods
specified in Note 1 to section 1.1 of ASTM D-93-71 may be used for the
respective materials specified in the note.
(c) For a liquid that is a mixture of compounds that have different
volatilities and flashpoints, its flashpoint shall be determined by
using the procedure specified in (a) or (b) of this subsection on the
liquid in the form it is shipped. If the flashpoint, as determined by
this test, is 100°F (37.8°C) or higher, an additional flashpoint determination
shall be run on a sample of the liquid evaporated to ninety percent
of its original volume, and the lower value of the two tests shall be
considered the flashpoint of the material.
(d) Organic peroxides, which undergo autoaccelerating thermal decomposition,
are excluded from any of the flashpoint determination methods specified
in this section.
(16) Hotel shall mean buildings or groups of buildings under
the same management in which there are sleeping accommodations for hire
primarily used by transients who are lodged with or without meals including
but not limited to inns, clubs, motels, and apartment hotels.
(17) Institutional occupancy shall mean the occupancy or use
of a building or structure or any portion thereof by persons harbored
or detained to receive medical, charitable or other care or treatment,
or by persons involuntarily detained.
(18) Liquid shall mean, for the purpose of these standards, any
material which has a fluidity greater than that of 300 penetration asphalt
when tested in accordance with ASTM Test for Penetration for Bituminous
Materials, D-5-65. When not otherwise identified, the term liquid shall
include both flammable and combustible liquids.
(19) "Combustible liquid" means any liquid having a flashpoint
at or above 100°F (37.8°C). Combustible liquids shall be divided into
two classes as follows:
(a) Class II liquids shall include those with flashpoints at or above
100°F (37.8°C) and below 140°F (60°C), except any mixture having components
with flashpoints of 200°F (93.3°C) or higher, the volume of which make
up ninety-nine percent or more of the total volume of the mixture.
(b) "Class III liquids" shall include those with flashpoints at or
above 140°F (60°C). Class III liquids are subdivided into two subclasses:
(i) "Class IIIA liquids" shall include those with flashpoints at or
above 140°F (60°C) and below 200°F (93.3°C) except any mixture having
components with flashpoints of 200°F (93.3°C) or higher, the total volume
of which make up ninety-nine percent or more of the total volume of
the mixture.
(ii) "Class IIIB liquids" shall include those with flashpoints at or
above 200°F (93.3°C). This section does not cover Class IIIB liquids.
Where the term "Class III liquids" is used in this section, it shall
mean only Class IIIA liquids.
(c) When a combustible liquid is heated for use to within 30°F (16.7°C)
of its flashpoint, it shall be handled in accordance with the requirements
for the next lower class of liquids.
(20) "Flammable liquid" means any liquid having a flashpoint below
100°F (37.8°C), except any mixture having components with flashpoints
of 100°F (37.8°C), or higher, the total of which make up ninety-nine percent
or more of the total volume of the mixture. Flammable liquids shall be
known as Class I liquids. Class I liquids are divided into three classes
as follows:
(a) Class IA shall include liquids having flashpoints below 73°F (22.8°C)
and having a boiling point below 100°F (37.8°C).
(b) Class IB shall include liquids having flashpoints below 73°F (22.8°C)
and having a boiling point at or above 100°F (37.8°C).
(c) Class IC shall include liquids having flashpoints at or above 73°F
(22.8°C) and below 100F (37.8°C).
(21) Unstable (reactive) liquid shall mean a liquid which in
the pure state or as commercially produced or transported will vigorously
polymerize, decompose, condense, or will become self-reactive under conditions
of shocks, pressure, or temperature.
(22) Low-pressure tank shall mean a storage tank which has been
designed to operate at pressures above 0.5 p.s.i.g. but not more than
15 p.s.i.g.
(23) Marine service station shall mean that portion of a property
where flammable or combustible liquids used as fuels are stored and dispensed
from fixed equipment on shore, piers, wharves, or floating docks into
the fuel tanks or self-propelled craft, and shall include all facilities
used in connection therewith.
(24) Mercantile occupancy shall mean the occupancy or use of
a building or structure or any portion thereof for the displaying, selling,
or buying of goods, wares, or merchandise.
(25) Office occupancy shall mean the occupancy or use of a building
or structure or any portion thereof for the transaction of business, or
the rendering or receiving of professional services.
(26) Portable tank shall mean a closed container having a liquid
capacity over sixty United States gallons and not intended for fixed installation.
(27) Pressure vessel shall mean a storage tank or vessel which
has been designed to operate at pressures above 15 p.s.i.g.
(28) Protection for exposure shall mean adequate fire protection
for structures on property adjacent to tanks, where there are employees
of the establishment.
(29) Refinery shall mean a plant in which flammable or combustible
liquids are produced on a commercial scale from crude petroleum, natural
gasoline, or other hydrocarbon sources.
(30) Safety can shall mean an approved container, of not more
than five gallons capacity, having a spring-closing lid and spout cover
and so designed that it will safely relieve internal pressure when subjected
to fire exposure.
(31) Vapor pressure shall mean the pressure, measured in pounds
per square inch (absolute) exerted by a volatile liquid as determined
by the "Standard Method of Test for Vapor Pressure of Petroleum Products
(Reid Method)," American Society for Testing and Materials ASTM D323-68.
(32) Ventilation as specified in these standards is for the prevention
of fire and explosion. It is considered adequate if it is sufficient to
prevent accumulation of significant quantities of vapor-air mixtures in
concentration over one-fourth of the lower flammable limit.
(33) Storage: Flammable or combustible liquids shall be
stored in a tank or in a container that complies with WAC
296-24-33009(2).
(34) Barrel shall mean a volume of forty-two United States gallons.
(35) Container shall mean any can, barrel, or drum.
(36) Approved unless otherwise indicated, approved, or listed by a nationally
recognized testing laboratory. Refer to federal regulation 29 CFR 1910.7
for definition of nationally recognized testing laboratory.
(37) Listed see subsection (36) of this section.
(38) "SUS" means Saybolt Universal Seconds as determined by the
Standard Method of Test for Saybolt Viscosity (ASTM D-88-56), and may
be determined by use of the SUS conversion tables specified in ASTM Method
D2161-66 following determination of viscosity in accordance with the procedures
specified in the Standard Method of Test for Viscosity of Transparent
and Opaque Liquids (ASTM D445-65).
(39) "Viscous" means a viscosity of 45 SUS or more.
Note: The volatility of liquids is increased when artificially heated
to temperatures equal to or higher than their flashpoints. When so heated
Class II and III liquids shall be subject to the applicable requirements
for Class I or II liquids. These standards may also be applied to high
flashpoint liquids when so heated even though these same liquids when
not heated are outside of its scope.
[Statutory Authority: Chapter 49.17 RCW.
88-23-054 (Order 88-25), 296-24-33001, filed 11/14/88. Statutory Authority:
RCW 49.17.040 and 49.17.050. 82-08-026 (Order 82-10), 296-24-33001, filed
3/30/82. Statutory Authority: RCW 49.17.040, 49.17.050, 49.17.240, chapters
43.22 and 42.30 RCW. 80-17-015 (Order 80-21), 296-24-33001, filed 11/13/80;
Order 76-29, 296-24-33001, filed 9/30/76; Order 76-6, 296-24-33001, filed
3/1/76; Order 74-27, 296-24-33001, filed 5/7/74; Order 73-5, 296-24-33001,
filed 5/9/73 and Order 73-4, 296-24-33001, filed 5/7/73.]
WAC 296-24-33003
Scope.
This section applies to the handling, storage, and use of flammable
and combustible liquids with a flash point below 200°F. This section does
not apply to:
(1) Bulk transportation of flammable and combustible liquids;
(2) Storage, handling, and use of fuel oil tanks and containers connected
with oil burning equipment;
(3) Storage of flammable and combustible liquids on farms.
(4) Liquids without flashpoints that may be flammable under some conditions,
such as certain halogenated hydrocarbons and mixtures containing halogenated
hydrocarbons;
(5) Mists, sprays, or foams, except flammable aerosols covered in WAC
296-24-33009; or
(6) Installations made in accordance with requirements of the following
standards:
(a) National Fire Protection Association Standard for Drycleaning Plants,
NFPA No. 32-1970;
(b) National Fire Protection Association Standard for the Manufacture
of Organic Coatings, NFPA No. 35-1970;
(c) National Fire Protection Association Standard for Solvent Extraction
Plants, NFPA No. 36-1967; or
(d) National Fire Protection Association Standard for the Installation
and Use of Stationary Combustion Engines and Gas Turbines, NFPA No.
37-1970.
[Statutory Authority: RCW 49.17.010, [49.17].050
and [49.17].060. 95-22-015, 296-24-33003, filed 10/20/95, effective 1/16/96.
Statutory Authority: Chapter 49.17 RCW. 94-06-068 (Order 93-17), 296-24-33003,
filed 3/2/94, effective 3/1/95; Order 73-5, 296-24-33003, filed 5/9/73
and Order 73-4, 296-24-33003, filed 5/7/73.]
WAC
296-24 Part E (Continued)
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