General Safety & Health Standards |
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WAC
296-24-510
Storage and handling of anhydrous ammonia.
296-24-51001
Scope.
296-24-51003
General.
296-24-51005
Definitions.
296-24-51007
Use of water in emergencies.
296-24-51009
Basic rules.
296-24-51011
Systems utilizing stationary, pier-mounted or skid-mounted aboveground
or underground, nonrefrigerated storage.
296-24-51013
Refrigerated storage.
296-24-51015
Systems utilizing portable DOT containers.
296-24-51017
Systems mounted on trucks, semi-trailers, and trailers for transportation
of ammonia.
296-24-51019
Systems mounted on farm wagons (implements of husbandry) for the transportation
of ammonia.
296-24-51021
Systems mounted on farm equipment (implements of husbandry) for the application
of ammonia.
296-24-51099
Appendix C--Availability of reference material.
WAC 296-24-510 Storage
and handling of anhydrous ammonia.
[Order 73-5, § 296-24-510, filed 5/9/73
and Order 73-4, § 296-24-510, filed 5/7/73.]
WAC 296-24-51001
Scope.
(1) This standard is intended to apply to the design, construction, location,
installation, and operation of anhydrous ammonia systems including refrigerated
ammonia storage systems.
(2) This standard does not apply to:
(a) Ammonia manufacturing plants.
(b) Refrigeration plants where ammonia is used solely as a refrigerant.
Such systems are covered in American National Standard Safety Code for
Mechanical Refrigeration, B-9.1. (See Appendix C for availability.)
The provisions of ANSI B-9.1 are not appropriate to refrigerated ammonia
storage systems as covered in this standard.
(c) Ammonia transportation pipelines.
[Order 73-5, § 296-24-51001, filed 5/9/73
and Order 73-4, § 296-24-51001, filed 5/7/73.]
WAC 296-24-51003
General.
(1) The term "anhydrous ammonia" as used in this standard refers to the
compound formed by a combination of two gaseous elements, nitrogen and
hydrogen, in the proportion of one part nitrogen to three parts hydrogen
by volume. Anhydrous ammonia may be in either gaseous or liquid form.
It is not to be confused with aqua ammonia which is a solution of ammonia
gas in water. Whenever the term "ammonia" appears in this standard, it
is understood to mean anhydrous ammonia.
(2) It is important that personnel understand the properties of this
gas and that they be thoroughly trained in safe practices for its storage
and handling. Some of the important physical properties of ammonia are
listed in (4) of this section.
(3) Gaseous ammonia liquefies under pressure at ambient temperature.
Advantage of this characteristic is taken by industry and for convenience
this commodity is usually shipped and stored under pressure as a liquid.
When refrigerated to or below its normal boiling point (-28°F) it may
be shipped and stored as a liquid at atmospheric pressure.
(4) Physical properties of ammonia:
| Molecular
symbol |
NH3 |
| Molecular
weight |
17.032 |
| Boiling point
at one atmosphere (one atmosphere = 14.7 psia) |
-28°F |
| Melting point
at one atmosphere |
-107.9°F |
| Critical temperature |
271.4°F |
| Critical pressure |
1657 psia |
| Latent heat
at -28°F and one atmosphere |
589.3 BTU
per pound |
| Relative density
of vapor compared to dry air at 32°F and one atmosphere |
0.5970 |
| Vapor density
at -28°F and one atmosphere |
0.05555 lb.per
cu. ft. |
| Specific gravity
of liquid at -28°F compared to water at 39.2°F |
0.6819 |
| Liquid density
at 28°F and one atmosphere |
42.57 lb.
per cu. ft. |
| Specific volume
of vapor at 32°F and one atmosphere |
20.78 cu.
ft. per pound |
| Flammable
limits by volume in air at atmospheric pressure |
16% to 25% |
| Ignition temperature
(in a standard quartz container) |
1562°F |
| Specific heat,
gas, 15 C, one atm at constant pressure, Cp |
0.5232 Btu/lb.
degree °F |
| at constant
volume, Cv |
0.3995 Btu/lb.
degree °F |
(5) Experience has shown that ammonia is extremely hard to ignite and
under normal conditions is a very stable compound. It takes temperatures
of 840-930°F to cause it to dissociate slightly at atmospheric pressure.
The flammable limits at atmospheric pressure are 16% to 25% by volume
of ammonia in air. Experiments conducted by a nationally recognized laboratory
indicated that an ammonia-air mixture in a standard quartz test container
does not ignite below 1562°F. Ammonia is classified by the United States
Department of Transportation and the U.S. Coast Guard as a nonflammable
compressed gas for the purpose of transportation.
(6) Ammonia should be handled only by properly trained personnel. In
no case shall ammonia be used in conjunction with chemicals unless the
possible reactions have first been adequately investigated. Under some
circumstances ammonia and ammonium compounds can form explosive products
with other chemicals. For additional information refer to NFPA 491M "Manual
on Hazardous Chemical Reactions" (see Appendix C for availability) and
CG-388, the "Chemical Data Guide for Bulk Shipment by Water" (1969 Edition).
(7) Ammonia gas irritates the skin and mucous membrane. At 50 ppm its
odor is detectable by most people. The maximum allowable concentration
for an 8 hour working exposure is specified as 50 PPM by the American
Conference of Government Industrial Hygienists. Because it serves as its
own warning agent, no person will voluntarily remain in concentrations
which are hazardous. At 5000 ppm it is rapidly fatal. Since ammonia gas
is lighter than air, adequate ventilation is the best means of preventing
any accumulation.
(8) The common metals are not attacked by dry ammonia. Zinc, copper and
copper base alloys such as brass are subject to rapid destructive action
by ammonia in the presence of water.
[Order 73-5, § 296-24-51003, filed 5/9/73
and Order 73-4, § 296-24-51003, filed 5/7/73.]
WAC 296-24-51005
Definitions.
The following definitions are applicable to all sections of this chapter
which include WAC 296-24-510 in the section number and shall be construed
to have the meanings below.
(1) "Approved" as used in these standards means:
(a) Listed by a recognized testing laboratory, or
(b) Recommended by the manufacturer as suitable for use with anhydrous
ammonia and so marked, or
(c) Accepted by the authority having jurisdiction.
(2) "Appurtenance" refers to all devices such as pumps, compressors,
safety relief devices, liquid-level gaging devices, valves and pressure
gages.
(3) "Capacity" refers to the total volume of the container measured in
U.S. gallons, unless otherwise specified.
(4) "Cylinder" means a container of 1000 pounds water capacity or less
constructed in accordance with United States Department of Transportation
Specifications.
(5) The "code" refers to the Unfired Pressure Vessel Code of the American
Society of Mechanical Engineers (Section VIII of the ASME Boiler Construction
Code), 1952, 1956, 1959, 1962, 1965, 1968 and 1971 editions, the joint
code of the American Petroleum Institute and the American Society of Mechanical
Engineers (API-ASME Code) 1951 edition, and subsequent amendments to or
later editions of the same, as adopted.
(6) "Container" includes all vessels, tanks, cylinders or spheres used
for transportation, storage or application of anhydrous ammonia.
(7) "Design pressure" is identical to the term "maximum allowable working
pressure" used in the code.
(8) An "implement of husbandry" is a farm wagon-type tank vehicle of
not over 3000 gallons capacity, used as a field storage "nurse tank" supplying
the fertilizer to a field applicator and moved on highways only for bringing
the fertilizer from a local source of supply to farms or fields or from
one farm or field to another.
(9) "Filling density" means the per cent ratio of the weight of the gas
in a container to the weight of water at 60°F that the container will
hold. One lb. H2O = 27.737 cu. in. at 60°F. For determining the weight
capacity of the tank in pounds, the weight of a gallon (231 cubic inches)
of water at 60°F in air shall be 8.32828 pounds.
(10) "Gas" refers to anhydrous ammonia in either the gaseous or liquefied
state.
(11) "Gas mask" refers to gas masks approved by the Mine Safety and Health
Administration (MSHA) and the National Institute for Occupational Safety
and Health (NIOSH).
(12) "DOT regulations" refer to hazardous materials regulations of the
department of transportation (Title 49-Transportation, Code of Federal
Regulations, Parts 171 to 190), including Specifications for Shipping
Containers.
(13) "Systems" as used in these standards refers to an assembly of equipment
consisting essentially of the container or containers, appurtenances,
pumps, compressors, and interconnecting piping.
(14) The abbreviations "psig" and "psia" refer to pounds per square inch
gage and pounds per square inch absolute, respectively.
(15) The terms "charging" and "filling" are used interchangeably and
have the same meaning.
(16) "Trailer" as used in these standards refers to every vehicle designed
for carrying property and for being drawn by a motor vehicle and so constructed
that no part of its weight except the towing device rests upon the towing
vehicle.
(17) "Tank motor vehicle" means any motor vehicle designed or used for
the transportation of anhydrous ammonia in any tank designed to be permanently
attached to any motor vehicle or any container not permanently attached
to any motor vehicle which by reason of its size, construction or attachment
to any motor vehicle must be loaded and/or unloaded without being removed
from the motor vehicle.
(18) "Semitrailer" refers to every vehicle designed for carrying property
and for being drawn by a motor vehicle and so constructed that some part
of its weight and that of its load rests upon or is carried by another
vehicle.
(19) "Safety relief valve" refers to an automatic spring loaded or equivalent
type pressure activated device for gas or vapor service characterized
by pop action upon opening, sometimes referred to as a pop valve. (Refer
to American National Standards Institute, Terminology for Pressure Relief
Devices, B95.1.)
(20) "Hydrostatic relief valve" refers to an automatic pressure activated
valve for liquid service characterized by throttle or slow weep opening
(nonpop action). (Refer to American National Standards Institute, Terminology
for Pressure Relief Devices, B95.1.)
[Statutory Authority: RCW 49.17.010, .040,
.050. 99-10-071 (Order 98-10), § 296-24-51005, filed 05/04/99, effective
09/01/99. Statutory Authority: Chapter 49.17 RCW. 94-15-096 (Order 94-07),
§ 296-24-51005, filed 7/20/94, effective 9/20/94; Order 74-27, § 296-24-51005,
filed 5/7/74; Order 73-5, § 296-24-51005, filed 5/9/73 and Order 73-4,
§ 296-24-51005, filed 5/7/73.]
WAC 296-24-51007
Use of water in emergencies.
(1) The concentration of ammonia vapor in air can effectively be reduced
by the use of adequate volumes of water applied through spray or fog nozzles.
(2) Water should be used on liquid ammonia spills only if sufficient
water is available. For the purpose of this section, sufficient water
may be taken to be 100 parts of water to one part of ammonia.
(3) If an ammonia container is exposed to fire and cannot be removed,
water should be used to cool it.
(4) Under some circumstances ammonia in a container is colder than the
available water supply. Under these circumstances water should not be
sprayed on the container walls since it would heat the ammonia and aggravate
any gas leak.
(5) If it is found necessary to dispose of ammonia, as from a leaking
container, liquid ammonia should be discharged into a vessel containing
water sufficient to absorb it. Sufficient water may be taken to be ten
parts of water per part ammonia. The ammonia should be injected into the
water as near the bottom of the vessel as practical.
[Order 73-5, § 296-24-51007, filed 5/9/73
and Order 73-4, § 296-24-51007, filed 5/7/73.]
WAC 296-24-51009
Basic rules.
This section applies to all sections of this chapter which include WAC
296-24-510 in the section number unless otherwise noted.
(1) Approval of equipment and systems. Each appurtenance shall be approved
in accordance with (a), (b), (c), and (d) of this subsection.
(a) It was installed before February 8, 1973 and was approved and tested,
and installed in accordance with either the provisions of the American
National Standard for the Storage and Handling of Anhydrous Ammonia,
K61.1, or the Fertilizer Institute Standards for the Storage and Handling
of Agricultural Anhydrous Ammonia, M-1, in effect at the time of installation;
or
(b) It is accepted, or certified, or listed, or labeled, or otherwise
determined to be safe by a nationally recognized testing laboratory;
or
(c) It is a type which no nationally recognized testing laboratory
does, or will undertake to accept, certify, list, label, or determine
to be safe; and such equipment is inspected or tested by any federal,
state, municipal, or other local authority responsible for enforcing
occupational safety provisions of a federal, state, municipal or other
local law, code, or regulation pertaining to the storage, handling,
transport, and use of anhydrous ammonia, and found to be in compliance
with either the provisions of the American National Standard for the
Storage and Handling of Anhydrous Ammonia, K61.1, or the Fertilizer
Institute Standards for the Storage and Handling of Agricultural Anhydrous
Ammonia, M-1, in effect at the time of installation; or
(d) It is a custom-designed and custom-built unit, which no nationally
recognized testing laboratory, or federal, state, municipal or local
authority responsible for the enforcement of a federal, state, municipal,
or local law, code or regulation pertaining to the storage, transportation
and use of anhydrous ammonia is willing to undertake to accept, certify,
list, label or determine to be safe, and the employer has on file a
document attesting to its safe condition following the conduct of appropriate
tests. The document shall be signed by a registered professional engineer
or other person having special training or experience sufficient to
permit him/her to form an opinion as to safety of the unit involved.
The document shall set forth the test bases, test data and results,
and also the qualifications of the certifying person.
(e) For the purposes of this section the word "listed" means that equipment
is of a kind mentioned in a list which is published by a nationally
recognized laboratory which makes periodic inspection of the production
of such equipment, and states such equipment meets nationally recognized
standards or has been tested and found safe for use in a specified manner.
"Labeled" means there is attached to it a label, symbol, or other identifying
mark of a nationally recognized testing laboratory which makes periodic
inspections of the production of such equipment, and whose labeling
indicates compliance with nationally recognized standards or tests to
determine safe use in a specified manner. "Certified" means it has been
tested and found by a nationally recognized testing laboratory to meet
nationally recognized standards or to be safe for use in a specified
manner, or is of a kind whose production is periodically inspected by
a nationally recognized testing laboratory, and it bears a label, tag,
or other record of certification.
(f) For purposes of this section, refer to federal regulation 29 CFR
1910.7 for definition of nationally recognized testing laboratory.
(2) Requirements for construction, original test and requalification
of not-refrigerated containers.
(a) Containers used with systems covered in WAC
296-24-51011 and 296-24-51017
through 296-24-51021
shall be constructed and tested in accordance with the code
except that construction under Table UW-12 at a basic joint
efficiency of under eighty percent is not authorized.
Containers built according to the code do not have to comply with paragraphs
UG-125 to UG-128, inclusive, and paragraphs UG-132 and UG-133 of the
code.
(b) Containers exceeding thirty-six inches in diameter or two hundred
fifty gallons water capacity shall be constructed to comply with one
or more of the following:
(i) Containers shall be stress relieved after fabrication in accordance
with the code, or
(ii) Cold-formed heads, when used, shall be stress relieved or,
(iii) Hot-formed heads shall be used.
(c) Welding to the shell, head, or any other part of the container
subject to internal pressure shall be done in compliance with
WAC
296-24-51005(5). Other welding is permitted only on saddle
plates, lugs, or brackets attached to the container by the container
manufacturer.
(d) Containers used with systems covered by subsection (3)(b)(iv) of
this section shall be constructed and tested in accordance with the
DOT specifications.
(e) The provisions of (a) of this subsection shall not be construed
as prohibiting the continued use or reinstallation of containers constructed
and maintained in accordance with the 1949, 1950, 1952, 1956, 1959,
1962, 1965 and 1968 editions of the Unfired Pressure Vessel Code of
the ASME or any revisions thereof in effect at the time of fabrication.
(3) Markings on nonrefrigerated containers and systems other than DOT
containers.
(a) System nameplates, when required, shall be permanently attached
to the system so as to be readily accessible for inspection and shall
include markings as prescribed in (b) of this subsection.
(b) Each container or system covered in WAC
296-24-51011, 296-24-51017,
296-24-51019
and 296-24-51021
shall be marked as specified in the following:
(i) With a marking identifying compliance with the rules of the code
under which the container is constructed.
(ii) With a notation on the container and system nameplate when the
system is designed for underground installation.
(iii) With the name and address of the supplier of the container
or the trade name of the container and with the date of fabrication.
(iv) With the water capacity of the container in pounds at 60°F or
gallons, United States standard.
(v) With the design pressure in pounds per square inch gage.
(vi) With the wall thickness of the shell and heads.
(vii) With marking indicating the maximum level to which the container
may be filled with liquid anhydrous ammonia at temperatures between
20°F and 100°F except on containers provided with fixed maximum level
indicators, such as fixed length dip tubes, or containers that are
filled by weight. Markings shall be in increments of not more than
20°F.
(viii) With the outside surface area in square feet.
(ix) With minimum temperature in Fahrenheit for which the container
is designed.
(x) Marking specified on container shall be on the container itself
or on a nameplate permanently affixed thereto.
(c) All main operating valves on permanently installed containers having
a capacity of over three thousand water gallons shall be identified
to show whether the valve is in liquid or vapor service. The recommended
method of identification may be legend or color code as specified in
(c)(i) and (ii) of this subsection:
(i) Legend: The legend liquid (or liquid valve), vapor (or vapor
valve), as appropriate, shall be placed on or within twelve inches
of the valve by means of a stencil tag, or decal.
(ii) Color code: Liquid valves shall be painted orange and vapor
valves shall be painted yellow. The legend orange-liquid, yellow-vapor
shall be displayed in one or more conspicuous places at each permanent
storage location. The legend shall have letters at least two inches
high and shall be placed against a contrasting background. This is
in accordance with American National Standard A13.1 "Schemes for Identification
of Piping Systems"-1956, Page 5.
(4) Marking refrigerated containers. (See WAC
296-24-51013(3). Marking refrigerated containers.)
(5) Location of containers.
(a) Consideration shall be given to the physiological effects of ammonia
as well as to adjacent fire hazards in selecting the location for a
storage container. Containers shall be located outside of buildings
or in buildings or sections thereof especially approved for this purpose.
(b) Containers shall be located at least fifty feet from a dug well
or other sources of potable water supply, unless the container is a
part of a water treatment installation.
(c) The location of permanent storage containers shall be outside densely
populated areas.
(d) Container locations shall comply with the following table:
| Minimum
Distances (feet) From Container to: |
| Normal Capacity of
Container |
Line of Adjoining
Property which may be built upon Highways & Mainline of
Railroad |
Place of Public Assembly |
Institution Occupancy |
| Over 500 to 2,000 |
25 |
150 |
250 |
| Over 2,000 to 30,000 |
50 |
300 |
500 |
| Over 30,000 to 100,000 |
50 |
450 |
750 |
| Over 100,000 |
50 |
600 |
1,000 |
(e) Storage areas shall be kept free of readily ignitable materials
such as waste, weeds and long dry grass.
(6) Container appurtenances.
(a) All appurtenances shall be designed for not less than the maximum
working pressure of that portion of the system on which they are installed.
All appurtenances shall be fabricated from materials proved suitable
for anhydrous ammonia service.
(b) All connections to containers except safety relief devices, gaging
devices, or those fitted with a No. 54 drill size orifice shall have
shutoff valves located as close to the container as practicable.
(c) Excess flow valves where required by these standards shall close
automatically at the rated flows of vapor or liquid as specified by
the manufacturer. The connections and line including valves and fittings
being protected by an excess flow valve shall have a greater capacity
than the rated flow of the excess flow valve.
(d) Liquid level gaging devices that require bleeding of the product
to the atmosphere and which are so constructed that outward flow will
not exceed that passed by a No. 54 drill size opening need not be equipped
with excess flow valves.
(e) Openings from container or through fittings attached directly on
container to which pressure gage connections are made need not be equipped
with excess flow valves if such openings are not larger than No. 54
drill size.
(f) Excess flow and back pressure check valves where required by these
standards shall be located inside of the container or at a point outside
as close as practicable to where the line enters the container. In the
latter case, installation shall be made in such manner that any undue
stress beyond the excess flow or back pressure check valve will not
cause breakage between the container and the valve.
(g) Excess flow valves shall be designed with a bypass, not to exceed
a No. 60 drill size opening to allow equalization of pressures.
(h) Shutoff valves provided with an excess flow valve shall be designed
for proper installation in a container connection so that the excess
flow valve will close should the shutoff valve break.
(i) All excess flow valves shall be plainly and permanently marked
with the name or trademark of the manufacturer, the catalog number,
and the rated capacity.
(7) Piping, tubing and fittings.
(a) All piping, tubing and fittings shall be made of material suitable
for anhydrous ammonia service.
(b) All piping, tubing and fittings shall be designed for a pressure
not less than the maximum pressure to which they may be subjected in
service.
(c) All piping shall be well supported and provision shall be made
for expansion and contraction. All refrigeration system piping shall
conform to the Refrigeration Piping Code (ANSI B31.5 1966 addenda B31.1a-1968),
a section of the American Standard Code for Pressure Piping, as it applies
to ammonia.
(d) Piping used on nonrefrigerated systems shall be at least ASTM A-53-1969
Grade B Electric Resistance Welded and Electric Flash Welded Pipe or
equal. Such pipe shall be at least Schedule 40 when joints are welded,
or welded and flanged. Such pipe shall be at least Schedule 80 when
joints are threaded. Brass, copper, or galvanized steel pipe or tubing
shall not be used.
(e) All metal flexible connections for permanent installations shall
have a minimum working pressure of 250 p.s.i.g. (safety factor of 4).
For temporary installations, hose meeting the requirement of subsection
(8) of this section may be used.
(f) Cast iron fittings must not be used, but this does not prohibit
the use of fittings made specifically for ammonia service, made of malleable,
nodular, or high-strength gray iron, meeting American Society for Testing
and Materials (SSTM) A-47-68, ASTM 395-68, or ASTM A126-66 Class B or
C.
(g) Provisions shall be made for expansion, contraction, jarring, vibration,
and for settling.
(h) Adequate provisions shall be made to protect all exposed piping
from physical damage that might result from moving machinery, the presence
of automobiles or trucks, or any other undue strain that may be placed
upon the piping.
(i) Joint compounds shall be resistant to ammonia.
(j) After assembly, all piping and tubing shall be tested and proved
to be free from leaks at a pressure not less than the normal operating
pressure of the system.
(8) Hose specification.
(a) Hose used in ammonia service and subject to container pressure
shall conform to the joint Rubber Manufacturers Association and the
Fertilizer Institute "Hose Specifications for Anhydrous Ammonia" (see
Appendix B).
(b) Hose subject to container pressure shall be designed for a minimum
working pressure of 350 p.s.i.g. and a minimum burst pressure of 1750
p.s.i.g. Hose assemblies, when made up, shall be capable of withstanding
a test pressure of 500 p.s.i.g.
(c) Hose and hose connections located on the low pressure side of flow
control or pressure reducing valves on devices discharging to atmospheric
pressure shall be designed for the maximum low side working pressure.
All connections shall be designed, constructed, and installed so that
there will be no leakage when connected.
(d) Where liquid transfer hose is not drained of liquid upon completion
of transfer operations, such hose shall be equipped with an approved
shutoff valve at the discharge end. Provision shall be made to prevent
excessive hydrostatic pressure in the hose. (See subsection (9)(j) of
this section.)
(e) On all hose one-half inch O.D. and larger, used for the transfer
of anhydrous ammonia liquid or vapor, there shall be etched, cast, or
impressed at five-foot intervals the following information:
"Anhydrous Ammonia"
xxx p.s.i.g. (Maximum working pressure)
Manufacturer's Name or Trademark
Year of Manufacture
(9) Safety relief devices.
(a) Every container used in systems covered by WAC
296-24-51011, 296-24-51017,
296-24-51019
and 296-24-51021
shall be provided with one or more safety relief valves of the
spring-loaded or equivalent type. The discharge from safety
relief valves shall be vented away from the container, upward
and unobstructed to the atmosphere. All safety relief valve
discharge openings shall have suitable raincaps that will allow
free discharge of the vapor and prevent the entrance of water.
Provision shall be made for draining condensate which may accumulate.
The rate of the discharge shall be in accordance with the provisions
of Appendix A.
(b) Container safety relief valves shall be set to start-to-discharge
as follows, with relations to the design pressure of the container.
| Containers |
Minimum |
Maximum* |
| ASME U-68,
U-69 |
110% |
125% |
| ASME U-200,
U-201 |
95% |
100% |
| ASME 1952,
1956, 1959, 1962, 1965, 1968, or 1971 |
95% |
100% |
| API-ASME |
95% |
100% |
| U.S. Coast
Guard |
(As required by U.S.CG regulations) |
| DOT |
(As required by DOT regulations) |
*Note: A relief valve manufacturer's tolerance of plus ten percent
is permitted.
(c) Safety relief devices used in systems covered by WAC
296-24-51011, 296-24-51017,
296-24-51019
and 296-24-51021
shall be constructed to discharge at not less than the rates
required in (a) of this subsection before the pressure is in
excess of one hundred twenty percent (not including the ten
percent tolerance referred to in (b) of this subsection) of
the maximum permitted start-to-discharge pressure setting of
the device.
(d) Safety relief valves shall be so arranged that the possibility
of tampering will be minimized. If the pressure setting adjustment is
external, the relief valves shall be provided with means for sealing
the adjustment.
(e) Shutoff valves shall not be installed between the safety
relief valves and the containers or systems described in WAC
296-24-51011,
296-24-51017, 296-24-51019
and 296-24-51021,
except that a shutoff valve may be used where the arrangement
of this valve is such as always to afford required capacity
flow through the relief valves.
Note: The above exception is made to cover such
cases as a threeway valve installed under two safety relief valves,
each of which has the required rate of discharge and is so installed
as to allow either of the safety relief valves to be closed off, but
does not allow both safety valves to be closed off at the same time.
Another exception to this may be where two separate relief valves are
installed with individual shutoff valves. In this case, the two shutoff
valve stems shall be mechanically interconnected in a manner which will
allow full required flow of one safety relief valve at all times. Still
another exception is a safety relief valve manifold which allows one
valve of two, three, four or more to be closed off and the remaining
valve or valves will provide not less than the rate of discharge shown
on the manifold nameplate.
(f) Safety relief valves shall have direct communication with the vapor
space of the container.
(g) Each safety relief valve used with systems described in
WAC
296-24-51011, 296-24-51017,
296-24-51019
and 296-24-51021
shall be plainly and permanently marked as follows:
(i) With the letters "AA" or the symbol "NH3."
(ii) The pressure in pounds per square inch gage (p.s.i.g.) at which
the valve is set to start-to-discharge.
(iii) The rate of discharge of the valve in cubic feet per minute
of air at 60°F and atmospheric pressure (14.7 p.s.i.a.).
(iv) The manufacturer's name and catalog number.
For example, a safety relief valve marked AA-250-4200 (air) would
mean that this valve is suitable for use on an anhydrous ammonia container;
that it is set to start-to-discharge at 250 p.s.i.g.; and that its
rate of discharge (see subsection (8)(a) through (c) of this section)
is four thousand two hundred cubic feet per minute of air.
(h) The flow capacity of the safety relief valve shall not be restricted
by any connection to it on either the upstream or downstream side.
(i) The manufacturer or supplier of a safety relief valve manifold
shall publish complete data showing the flow rating through the combined
assembly of the manifold with safety relief valves installed. The manifold
flow rating shall be determined by testing the manifold with all but
one valve discharging. If one or more openings have restrictions not
present in the remaining openings, the restricted opening or openings
or those having the lowest flow shall be used to establish the flow
rate marked on the manifold nameplate. The marking shall be similar
to that required in (g) of this subsection for individual valves.
(j) A hydrostatic relief valve shall be installed between each pair
of valves in the liquid ammonia piping or hose where liquid may be trapped
so as to relieve into the atmosphere at a safe location.
(k) Discharge from safety relief devices shall not terminate in or
beneath any building.
(10) Safety. See CGA Pamphlet G-2, TFI Operational Safety Manual M-2
and MCA Safety Data Sheet SD-8 (see Appendix C for availability).
(a) Personnel required to handle ammonia shall be trained in safe operating
practices and the proper action to take in the event of emergencies.
Personnel shall be instructed to use the equipment listed in (c) of
this subsection in the event of an emergency. (Rev. 1-22-76)
(b) If a leak occurs in an ammonia system, the personnel trained for
and designated to act in such emergencies shall:
(i) See that persons not required to deal with an emergency are evacuated
from the contaminated area.
(ii) Put on a suitable gas mask.
(iii) Wear gauntlet type plastic or rubber gloves and wear plastic
or rubber suits in heavily contaminated atmospheres.
(iv) Shut off the appropriate valves.
(c) All stationary storage installations shall have at least:
(i) Two suitable gas masks in readily accessible locations. Full
face masks with ammonia canisters as certified by NIOSH under 42 CFR
Part 84, are suitable for emergency action for most leaks, particularly
those that occur outdoors. For protection in concentrated ammonia
atmospheres self-contained breathing apparatus is required.
(ii) One pair of protective gloves made of rubber or other material
impervious to ammonia.
(iii) One pair of protective boots made of rubber or other material
impervious to ammonia.
(iv) One protective slicker and/or protective pants and jacket made
of rubber or other material impervious to ammonia.
(v) Easily accessible shower and/or at least fifty gallons of clean
water in an open top container.
(vi) Tight fitting vented goggles or one full face shield.
(d) Where several persons are usually present, additional safety equipment
may be desirable.
(e) Each tank motor vehicle transporting anhydrous ammonia, except
farm applicator vehicles, shall carry a container of at least five gallons
of water and shall be equipped with a full face gas mask, a pair of
tight-fitting goggles or one full face shield. The driver shall be instructed
in their use and the proper action to take to provide for his/her safety.
(f) If a leak occurs in transportation equipment and it is not practical
to stop the leak, the driver should move the vehicle to an isolated
location away from populated communities or heavily traveled highways.
(g) If liquid ammonia contacts the skin or eyes, the affected area
should be promptly and thoroughly flushed with water. Do not use neutralizing
solutions or ointments on affected areas. A physician shall treat all
cases of eye exposure to liquid ammonia.
(11) Filling densities. (See WAC
296-24-51005(9).)
(a) The filling densities for nonrefrigerated containers shall not
exceed the following:
| |
Aboveground |
Underground |
| (i) Uninsulated |
56%* |
58% |
| (ii) Insulated |
57% |
|
| (iii) DOT
containers shall be filled in accordance with DOT regulations. |
*This corresponds to 82% by volume at -28°F, 85% by volume at 5°F,
87.5% by volume at 30°F, and 90.6% by volume at 60°F.
(b) The filling density for refrigerated storage tanks temperature
corresponding to the vapor pressure at the start-to-discharge pressure
setting of the safety relief valve.
(c) If containers are to be filled according to liquid level by any
gaging method other than a fixed length dip tube gage, each container
should have a thermometer well so that the internal liquid temperature
can be easily determined and the amount of liquid and vapor in the container
corrected to a 60°F basis.
(12) Transfer of liquids.
(a) Anhydrous ammonia shall always be at a temperature suitable for
the material of construction and design of the receiving containers.
Ordinary steels are not suitable for refrigerated ammonia. See Appendix
R of API Standard 620 "Recommended Rules for Design and Construction
of Large Welded Low-Pressure Storage Tanks" for materials for low temperature
service.
(b) At least one attendant shall supervise the transfer of liquids
from the time the connections are first made until they are finally
disconnected.
(c) Flammable gases or gases which will react with ammonia (such as
air) shall not be used to unload tank cars or transport trucks.
(d) Containers shall be charged or used only upon authorization of
the owner.
(e) Containers shall be gaged and charged only in the open atmosphere
or in buildings approved for that purpose.
(f) Pumps used for transferring ammonia shall be recommended and labeled
for ammonia service by the manufacturer.
(i) Pumps shall be designed for at least 250 p.s.i.g. working pressure.
(ii) Positive displacement pumps shall have installed, off the discharge
port, a constant differential relief valve discharging into the suction
port of the pump through a line of sufficient size to carry the full
capacity of the pump at relief valve setting, which setting and installation
shall be according to pump manufacturer's recommendations.
(iii) On the discharge side of the pump, before the relief valve
line, there shall be installed a pressure gage graduated from 0 to
400 p.s.i.g.
(iv) Plant piping shall contain shutoff valves located as close as
practical to pump connections.
(g) Compressors used for transferring or refrigerating ammonia shall
be recommended and labeled for ammonia service by the manufacturer.
(i) Compressors, except those used for refrigeration, shall be designed
for at least 250 p.s.i.g. working pressure. Crank cases of compressors
not designed to withstand system pressure shall be protected with
a suitable safety relief valve.
(ii) Plant piping shall contain shutoff valves located as close as
practical to compressor connections.
(iii) A safety relief valve large enough to discharge the full capacity
of the compressor shall be connected to the discharge before any shutoff
valve.
(iv) Compressors shall have pressure gages at suction and discharge
graduated to at least one and one-half times the maximum pressure
that can be developed.
(v) Adequate means, such as drainable liquid trap, may be provided
on the compressor suction to minimize the entry of liquid into the
compressor.
(vi) Where necessary to prevent contamination, an oil separator shall
be provided on the discharge side of the compressor.
(h) Loading and unloading systems shall be protected by suitable devices
to prevent emptying of the storage container or the container being
loaded or unloaded in the event of severance of the hose. Backflow check
valves or properly sized excess flow valves shall be installed where
necessary to provide such protection. In the event that such valves
are not practical, remotely operated shutoff valves may be installed.
(i) Meters used for the measurement of liquid anhydrous ammonia shall
be recommended and labeled for ammonia service by the manufacturer.
(i) Liquid meters shall be designed for a minimum working pressure
of 250 p.s.i.g.
(ii) The metering system shall incorporate devices that will prevent
the inadvertent measurement of vapor.
(13) Tank car unloading points and operations.
(a) Provisions for unloading tank cars shall conform to the regulations
of the department of transportation.
(b) Unloading operations shall be performed by reliable persons properly
instructed and made responsible for careful compliance with all applicable
procedures.
(c) Caution signs shall be so placed on the track or car as to give
necessary warning to persons approaching car from open end or ends of
siding and shall be left up until after car is unloaded and disconnected
from discharge connections. Signs shall be of metal or other suitable
material, at least twelve by fifteen inches in size and bear the words
"stop-Tank car connected" or "stop-Men at work" the word "stop," being
in letters at least four inches high and the other words in letters
at least two inches high. The letters shall be white on a blue background.
(d) The track of a tank car siding shall be substantially level.
(e) Brakes shall be set and wheels blocked on all cars being unloaded.
(f) Tank cars of anhydrous ammonia shall be unloaded only at approved
locations meeting the requirements of subsections (9)(c) and (12)(h)
of this section.
(14) Liquid level gaging device.
(a) Each container except those filled by weight shall be equipped
with an approved liquid level gaging device.
(b) All gaging devices shall be arranged so that the maximum liquid
level to which the container is filled is readily determined. (See subsection
(4)(b)(vii) of this section.)
(c) Gaging devices that require bleeding of the product to the atmosphere
such as the rotary tube, fixed tube, and slip tube devices, shall be
designed so that the maximum opening of the bleed valve is not larger
than No. 54 drill size unless provided with an excess flow valve. (This
requirement does not apply to farm vehicles used for the application
of ammonia as covered in WAC 296-24-51021.)
(d) Gaging devices shall have a design pressure equal to or greater
than the design pressure of the container on which they are installed.
(e) Fixed liquid level gages shall be so designed that the maximum
volume of the container filled by liquid shall not exceed eighty-five
percent of its water capacity. The coupling into which the fixed liquid
level gage is threaded must be placed at the eighty-five percent level
of the container. If located elsewhere, the dip tube of this gage must
be installed in such a manner that it cannot be readily removed.
Note: This does not apply to refrigerated storage.
(f) Gage glasses of the columnar type shall be restricted to stationary
storage installation. They shall be equipped with shutoff valves having
metallic handwheels, with excess-flow valves, and with extra heavy glass
adequately protected with a metal housing applied by the gage manufacturer.
They shall be shielded against the direct rays of the sun.
(15) Painting of containers. Aboveground uninsulated containers should
have a reflective surface maintained in good condition. White is recommended
for painted surfaces, but other light reflecting colors are acceptable.
(16) Electrical equipment and wiring.
(a) Electrical equipment and wiring for use in ammonia installations
shall be general purpose or weather resistant as appropriate.
(b) Where concentrations of ammonia in air in excess of sixteen percent
by volume are likely to be encountered, electrical equipment
and wiring shall be of a type specified by and be installed
according to
chapter 296-24 WAC Part L, for Class I, Group D locations.
[Statutory Authority: RCW 49.17.010,
.040, .050. 02-12-098 (Order 00-20), § 296-24-51009, filed 06/05/02,
effective 08/01/02.Statutory Authority: RCW 49.17.010, .040, .050. 99-10-071
(Order 98-10), § 296-24-51009, filed 05/04/99, effective 09/01/99. Statutory
Authority: Chapter 49.17 RCW. 91-24-017 (Order 91-07), § 296-24-51009,
filed 11/22/91, effective 12/24/91; 88-23-054 (Order 88-25), § 296-24-51009,
filed 11/14/88. Statutory Authority: RCW 49.17.040, 49.17.050, 49.17.240,
chapters 43.22 and 42.30 RCW. 80-17-015 (Order 80-21), § 296-24-51009,
filed 11/13/80; Order 76-6, § 296-24-51009, filed 3/1/76; Order 74-27,
§ 296-24-51009, filed 5/7/74; Order 73-5, § 296-24-51009, filed 5/9/73
and Order 73-4, § 296-24-51009, filed 5/7/73.]
WAC 296-24-51011
Systems utilizing stationary, pier-mounted or skid-mounted aboveground
or underground, nonrefrigerated storage.
This section applies to stationary, pier-mounted, skid-mounted, aboveground
or underground, nonrefrigerated storage installations utilizing
containers other than those constructed in accordance with department
of transportation specifications. All basic rules of WAC
296-24-51009 apply to this section unless otherwise noted.
(1) Design pressure and construction of containers. The minimum design
pressure for nonrefrigerated aboveground containers must be 250
psig. (See WAC
296-24-51009 (2)(a).)
Note: U-68 and U-69 ASME Code containers with a
design pressure of 200 psig are acceptable if recertified to 250
psig and equipped with safety relief valves set at 250 psig as
permitted in WAC
296-24-51009 (9)(b).
(2) Container valves and accessories, filling and discharging connections.
(a) Each filling connection shall be provided with combination back-pressure
check valve and excess flow valve; one double or two single back-pressure
check valves; or a positive shutoff valve in conjunction with either
an internal back-pressure check valve or an internal excess flow valve.
(b) All vapor and liquid connections, except safety relief valves and
those specifically exempt in WAC
296-24-51009 (6)(d) and (e) shall be equipped with approved
excess flow valves; or in lieu thereof, may be fitted with approved
quick-closing internal valves which, except during operating
periods, shall remain closed.
(c) Each storage container shall be provided with a pressure gage graduated
from 0 to 400 psig. Gages shall be designated for use in ammonia service.
(d) All containers shall be equipped with an approved vapor return
valve.
(e) All containers shall be equipped with a fixed maximum liquid level
gage.
(3) Safety relief devices.
(a) Every container shall be provided with one or more safety relief
valves of spring-loaded or equivalent type and shall comply with the
following:
(i) The discharge from safety relief valves shall be directed away
from the container upward and unobstructed to the open air. Vent pipes
shall not be restrictive or smaller in size than the safety relief
outlet connection. All safety relief valve discharges shall have suitable
rain caps that will allow free discharge of the vapor and prevent
the entrance of water. Suitable provision shall be made for draining
condensate which may accumulate.
(ii) If desired, vent pipes from two or more safety relief devices
located on the same unit, or similar lines from two or more different
units, may be run into a common header, provided the cross-sectional
area of such header is at least equal to the sum of the cross-sectional
areas of the individual vent pipes.
(b) The rate of discharge of spring-loaded safety relief valves installed
on underground containers may be reduced to a minimum of 30 percent
of the rate of discharge specified in Appendix A. Containers so protected
shall not be uncovered after installation until the liquid ammonia has
been removed. Containers which may contain liquid ammonia before being
installed underground and before being completely covered with earth
are to be considered aboveground containers when determining the rate
of discharge requirements of the safety relief valves.
(c) On underground installations where there is a probability of the
manhole or housing becoming flooded, the discharge from vent lines shall
be located above the high water level. All manholes or housings shall
be provided with ventilated louvres or their equivalent, the area of
such openings equaling or exceeding combined discharge areas of safety
relief valves and vent lines which discharge their content into the
manhole housing.
(4) Installation of storage containers.
(a) Containers installed aboveground shall be provided with substantial
reinforced concrete footings and foundations or structural steel
supports mounted on reinforced concrete foundations. In either
case, the reinforced concrete foundations or footings shall
extend below the established frost line and shall be of sufficient
width and thickness to support the total weight of the containers
and contents adequately. The foundation shall maintain the lowest
point of the tank at not less than 18 inches above the ground.
Floating type foundations shall also be acceptable providing
the foundations are designed to adequately support the tank,
contents and pumping equipment. (See WAC
296-24-51009(7).)
(b) Horizontal aboveground containers shall be mounted on foundations
in such a manner as to permit expansion and contraction. Every container
shall be supported so as to prevent the concentration of excessive loads
on the supporting portion of the shell. The bearing afforded by the
saddles shall extend over at least one third of the circumference of
the shell. Suitable means for preventing corrosion shall be provided
on that portion of the container in contact with the foundations or
saddles.
(c) Containers buried underground shall be placed so that the top of
the container is at least one foot below the surface of the ground.
Should ground conditions make compliance with these requirements impracticable,
precautions shall be taken to prevent physical damage to the container.
It is not necessary to cover the portion of the container to which a
manhole and other connections are affixed when necessary to prevent
floating, containers shall be securely anchored or weighted.
(d) Underground containers shall be set on firm foundations (firm earth
may be used) and surrounded with soft earth or sand well tamped in place.
As a further means of resisting corrosion, the container, prior to being
placed underground, shall be given a protective coating satisfactory
to the authority having jurisdiction. Such protective coating shall
be equivalent to hot dip galvanizing, or to two preliminary coatings
of red lead followed by a heavy coating of coal tar or asphalt. The
container thus coated shall be lowered into place in such a manner as
to prevent abrasion or other damage to the coating.
(e) Distance between aboveground and underground containers of over
1,200 gallons capacity shall be at least five feet.
(f) Secure anchorage or adequate pier height shall be provided against
container flotation wherever sufficiently high flood water might occur.
(5) Reinstallation of containers.
(a) Containers once installed underground shall not later be reinstalled
aboveground or underground, unless they successfully withstand hydrostatic
pressure retests at the pressure specified for the original hydrostatic
test as required by the code under which the tank was constructed and
show no evidence of serious corrosion.
(b) Where containers are reinstalled underground, the corrosion
resistant coating shall be put in good condition; see WAC
296-24-51011 (4)(d). Where containers are reinstalled aboveground,
safety relief devices or gaging devices shall comply with WAC
296-24-51009(9) and 296-24-51011(3)
respectively for aboveground containers.
(6) Marking of containers. Each container or group of containers shall
be marked on at least two sides with the words "anhydrous ammonia" or
"caution-ammonia" in sharply contrasting colors with letters not less
than four inches high.
(7) Protection of container appurtenances.
(a) Valves and other appurtenances shall be protected against physical
damage. Main container shut-off valves shall be kept closed and locked
when the installation is unattended. If the facility is protected against
tampering by fencing or other suitable means, valve locks are not required.
(b) All connections to underground containers should be located within
a substantial dome, housing or manhole fitted with a substantial removable
cover. Appurtenances shall also be protected during the transit of containers
intended for installation underground.
(c) Storage containers need not be grounded.
(8) Identification. A sign shall be displayed in a conspicuous place
stating the name, address, and phone number of the nearest representative,
agent, or owner of the storage system.
[Statutory Authority: RCW 49.17.010,
.040, .050. 02-12-098 (Order 00-20), § 296-24-51011, filed 06/05/02,
effective 08/01/02. Order 76-6, § 296-24-51011, filed 3/1/76; Order
73-5, § 296-24-51011, filed 5/9/73 and Order 73-4, § 296-24-51011, filed
5/7/73.]
WAC 296-24-51013
Refrigerated storage.
This section applies specifically to systems utilizing tanks for the
storage of anhydrous ammonia under refrigerated conditions. All
basic rules of WAC
296-24-51009 apply to this section unless inconsistent with
the requirements of this section.
(1) Design of tanks.
(a) Tanks may be designed for any storage pressure desired as determined
by economical design of the refrigerated system.
(b) The design temperature shall be the minimum temperature to which
the container will be refrigerated and shall be so designated.
(c) Containers with a design pressure exceeding 15 p.s.i.g. shall be
constructed in accordance with WAC
296-24-51009(2) and the material shall be selected from
those listed in API Standards 620, 4th edition 1970, Recommended
Rules for Design and Construction of Large, Welded Low-Pressure
Storage Tanks, Tables 2.02, R.2.1, R.2.2, R.2.3 or R.2.4.
(d) Tanks with a design pressure of 15 p.s.i.g. and less shall be constructed
in accordance with the general requirements of API Standard 620, 4th
edition, 1970, including Appendix R.
(e) When austenitic steels or nonferrous materials are used, the ASME
Code shall be used as a guide in selection of materials for use at the
design temperature.
(f) The filling density for refrigerated storage containers shall be
such that the container will not be liquid full at a liquid temperature
corresponding to the vapor pressure at the start-to-discharge pressure
setting of the safety-relief valve. (New 1-22-76)
(2) Installation of storage tanks.
(a) Tanks shall be supported on suitable noncombustible foundations
designed to accommodate the type of tank being used.
(b) Adequate protection against flotation or other water damage shall
be provided wherever high flood water might occur.
(c) Tanks for product storage at less than 32°F shall be supported
in such a way, or heat shall be supplied, to prevent the effects of
freezing and consequent frost heaving.
(d) The area surrounding a refrigerated tank or group of tanks shall
be provided with drainage, or shall be diked to prevent accidental discharge
of liquid from spreading to uncontrolled areas.
(e) When drainage is employed, a slope of not less than one percent
shall be provided. The drainage system shall terminate in an impounding
basin having a capacity as large as the largest tank served.
(f) Provision shall be made for drainage of rain water from the diked
or impounding area. Such drainage shall not permit the release of ammonia.
(g) When a dike surrounding the tank is employed, the capacity of the
diked enclosure shall be as large as the largest tank served.
(h) The walls of a diked enclosure or the wall of an impounding basin
used in a drainage system shall be of earth, steel or concrete designed
to be liquid tight and to withstand the hydrostatic pressure and the
temperature. Earth walls shall have a flat top at least 2 feet wide.
The slope shall be stable and consistent with the angle of repose of
the earth used.
(i) The ground in an impounding basin or within a diked enclosure,
should be graded so that small spills, or the early part of a large
spill, will accumulate at one side or corner contacting a relatively
small area of ground and exposing a relatively small surface area
for heat gain. Shallow channels in the ground surface or low curbs
of earth can help guide the liquid to these low areas without contacting
a large ground area.
(3) Marking refrigerated containers.
Each refrigerated container shall be marked with a nameplate on the outer
covering in an accessible place as specified in the following:
(a) With the name and address of the builder and the date of fabrication.
(b) With the maximum volume or weight of the product whichever is most
meaningful to user.
(c) With the design pressure.
(d) With the minimum temperature in degrees Fahrenheit for which the
container was designed.
(e) With the maximum allowable water level to which the container may
be filled for the test purposes.
(f) With the density of the product in pounds per cubic foot for which
the container was designed.
(g) With the maximum level to which the container may be filled with
liquid anhydrous ammonia.
(4) Tank valves, fill pipes and discharge pipes.
(a) Shut-off valves shall be:
(i) Provided for all connections except those with a No. 54 drill
size restriction, plugs, safety valves, thermometer wells, and
(ii) Located as close to the tank as practicable.
(b) When operating conditions make it advisable, a check valve shall
be installed on the fill connection and a remotely operated shut-off
valve on other connections located below the maximum liquid level.
(5) Safety relief devices.
(a) Safety relief valves shall be set to start-to-discharge at a pressure
not in excess of the design pressure of the tank and shall have a total
relieving capacity sufficient to prevent a maximum pressure in a tank
of more than one hundred twenty percent of the design pressure.
(b) The total relieving capacity shall be the larger requirement of
(b)(i) or (ii) of this subsection.
(i) Possible refrigeration system upset such as (A) cooling water
failure, (B) power failure, (C) instrument air or instrument failure,
(D) mechanical failure of any equipment, (E) excessive pumping rates,
(F) changing atmospheric conditions.
(ii) Either one of the following formulas for fire exposure, (A)
for valve manufacturers who use weight of vapors to be relieved as
basis for classifying valves:
34,500 F A0.82
W = __________________
L
or (B) for valve manufacturers that classify valves on the basis
of air flow:
633,000 F AO.82
Qa = ___________________
L C

Where
W = weight of vapors to be relieved in pounds/hour at relieving
conditions;
Qa = air flow in cubic feet per minute at standard conditions (60F
and 14.7 psi);
F = fireproofing credit. Use F = 1.0 except when an approved fireproofing
material of recommended thickness is used, then use F = 0.2.
A = total surface area in square feet up to 25 feet above grade
or to the equator of a sphere, whichever is greater;
Z = compressibility factor of ammonia at relieving conditions (if
not known, use Z = 1.0);
T = temperature in degrees R (460 + temperature in degrees F of
gas at relieving conditions);
M = molecular weight = 17 for ammonia;
L = latent heat of ammonia at relieving conditions;
C = constant based on relation of specific heats. (C may be obtained
from the following table.)
(If K is not known use C = 315.)
| K |
C |
K |
C |
K |
C |
| 1.00 |
315 |
1.26 |
343 |
1.52 |
366 |
| 1.02 |
318 |
1.28 |
345 |
1.54 |
368 |
| 1.04 |
320 |
1.30 |
347 |
1.56 |
369 |
| 1.06 |
322 |
1.32 |
349 |
1.58 |
371 |
| 1.08 |
324 |
1.34 |
351 |
1.60 |
372 |
| 1.10 |
327 |
1.36 |
352 |
1.62 |
374 |
| 1.12 |
329 |
1.38 |
354 |
1.64 |
376 |
| 1.14 |
331 |
1.40 |
356 |
1.66 |
377 |
| 1.16 |
333 |
1.42 |
358 |
1.68 |
379 |
| 1.18 |
335 |
1.44 |
359 |
1.70 |
380 |
| 1.20 |
337 |
1.46 |
361 |
2.00 |
400 |
| 1.22 |
339 |
1.48 |
363 |
2.20 |
412 |
| 1.24 |
341 |
1.50 |
364 |
|
|
Where K = Cp/Cv at atmospheric conditions
and
Cp = specific heat of vapor at constant pressure.
Cv = specific heat of vapor at constant volume.
(c) Shut-off valves of adequate flow capacity may be provided and used
to facilitate inspection and repair of safety relief valves. When a
shut-off valve is provided it shall be so arranged that it can be locked
or sealed open, and it shall not be closed except by an authorized person
who shall remain stationed there while the valve remains closed, and
who shall again lock or seal the valve open when leaving the station.
(d) Safety relief devices shall comply with the following:
(i) If stacks are used they shall be suitably designed to prevent
obstruction by rain, snow, ice or condensate. The outlet size shall
not be smaller than the nominal size of the safety relief valve outlet
connection.
(ii) Discharge lines may be used if desired. Multiple safety relief
valves on the same storage unit may be run into a common discharge
header. The discharge line and header shall be designed to accommodate
the maximum flow and a back pressure not exceeding ten percent of
the design pressure of the storage container. This back pressure shall
be included in the one hundred twenty percent total maximum pressure
given in (a) of this subsection. No other container or system shall
exhaust into this discharge line or header. The vent lines shall be
installed to prevent accumulation of liquid in the lines.
(e) Atmospheric storage shall be provided with vacuum breakers. Ammonia
gas may be used to provide a pad.
(6) Protection of container appurtenances. Refrigerated storage containers
shall comply with the provisions of WAC
296-24-51011(7).
(7) Reinstallation of containers. Containers of such size as to require
field fabrication shall, when moved and reinstalled, be reconstructed
and reinspected in complete accordance with the code under which they
were constructed. The containers shall be subjected to a pressure retest,
and if rerating is necessary, it shall be done in accordance with the
applicable code pressures.
(8) Damage from vehicles. Precaution shall be taken to avoid any damage
by trucks, tractors, or other vehicles.
(9) Refrigeration load and equipment.
(a) The total refrigeration load shall be computed as the sum of the
following:
(i) Load imposed by heat flow into the container caused by the temperature
differential between the ambient temperature and the design storage
temperature.
(ii) Load imposed by heat flow into the tank caused by maximum sun
radiation.
(iii) Maximum load imposed by filling the tank with ammonia warmer
than the design storage temperature.
(b) More than one storage tank may be handled by the same refrigeration
system.
(c) Compressors. (See also WAC
296-24-51009 (12)(g).)
(i) A minimum of two compressors shall be provided, either of which
is of sufficient size to handle the loads listed in (a)(i) and (ii)
of this subsection. Where more than two compressors are provided,
minimum standby equipment equal to the largest normally operating
equipment shall be installed. Compressors required for (a)(iii) of
this subsection may be used as standby equipment for compressors required
in (a)(i) and (ii) of this subsection.
(ii) Compressors shall be sized to operate with a suction pressure
at least ten percent below the minimum setting of the safety relief
valve(s) on the storage tank and shall withstand a suction pressure
at least equal to one hundred twenty percent of the design pressure
of the tank. Discharge pressure will be governed by condensing conditions.
(d) Compressor drives.
(i) Each compressor shall have its individual driving unit.
(ii) Any standard drive consistent with good design may be used.
(iii) An emergency source of power of sufficient capacity to handle
the loads listed in (a)(i) and (ii) of this subsection shall be provided,
unless facilities are provided to safely dispose of vented vapors
while the refrigeration system is not operating.
(e) Automatic control equipment.
(i) The refrigeration system shall be arranged with suitable controls
to govern the compressor operation in accordance with the load as
evidenced by the pressure in the container(s).
(ii) An emergency alarm system shall be installed to function in
the event the pressure in the container(s) rises to the maximum or
falls to the minimum allowable operating pressure.
(iii) An emergency alarm and shut-off shall be located in the condenser
system to respond to excess discharge pressure caused by failure of
the cooling medium.
(iv) All automatic controls shall be installed in a manner to preclude
operation of alternate compressors unless the controls will function
with the alternate compressors.
(f) Separators.
(i) An entrainment separator of suitable size and design pressure
shall be installed in the compressor suction line. The separator shall
be equipped with a drain and gaging device.
(ii) An oil separator of suitable size shall be installed in the
compressor discharge line. It shall be designed for at least 250 p.s.i.g.
and shall be equipped with a gaging device and drain valve.
(g) Condensers. The condenser system may be cooled by air or water
or both. The condenser shall be designed for at least 250 p.s.i.g. Provision
shall be made for purging noncondensibles either manually or automatically.
(h) Receiver and liquid drain. A receiver shall be provided which is
equipped with an automatic float valve to discharge the liquid ammonia
to storage or with a high pressure liquid drain trap of suitable capacity.
The receiver shall be designed for at least 250 p.s.i.g. operating pressure
and be equipped with the necessary connections, safety relief valves
and gaging device.
(i) Insulation. Refrigerated containers and pipe lines which are insulated
shall be covered with a material of suitable quality and thickness for
the temperatures encountered. Insulation shall be suitably supported
and protected against the weather. Weatherproofing shall be of a type
which will not support flame propagation.
(10) Safety equipment. All refrigerated storage plants shall have on
hand the minimum safety equipment required under WAC
296-24-51009 (10)(c).
[Statutory Authority: Chapter 49.17 RCW.
88-23-054 (Order 88-25), § 296-24-51013, filed 11/14/88. Statutory Authority:
RCW 49.17.040, 49.17.050, 49.17.240, chapters 43.22 and 42.30 RCW. 80-17-015
(Order 80-21), § 296-24-51013, filed 11/13/80; Order 76-6, § 296-24-51013,
filed 3/1/76; Order 73-5, § 296-24-51013, filed 5/9/73 and Order 73-4,
§ 296-24-51013, filed 5/7/73.]
WAC
296-24 Part F-2 Continued
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